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10507 15243-33-1 Dodecacarbonyltriruthenium, 99% Ruthenium carbonyl Triruthenium dodecacarbonyl Alfa Aesar

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10507
Dodecacarbonyltriruthenium, 99%

CAS: 15243-33-1 MDL: MFCD00011209  EINECS: 239-287-4
UN#:UN3466Hazard Class:6.1Packing Group:III
Alternate Name: Ruthenium carbonyl
Triruthenium dodecacarbonyl

 

Pricing and Availability

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Chemical Properties

Formula: C12O12Ru3  Melting point: ca 150° dec.
Formula weight: 639.33  Solubility: Sparingly soluble in hydrocarbons (e.g. hexane, cyclohexane, benzene) and acetone. Solutions undergo some decomposition on strong heating
Form: Crystalline 

Literature References

1,6-Enynes undergo cyclocondensation with CO under pressure, to give bicyclo[3.3.0]octenones: J. Org. Chem., 62, 3762 (1997):

On heating under pressure with norbornene and CO, alkynes undergo aromatization to give condensed hydroquinones: Organometallics, 17, 766 (1998). For reaction scheme, see 2-Hexyne, B22405.


Applications

Carbonylation

Other References

UN#: UN3466
Harmonized Tariff Code: 2843.90

GHS Hazard and Precautionary Statements

Hazard Statements : H331

Toxic if inhaled.

Precautionary Statements : P261-P304+P340-P311-P405-P403+P233-P501A

Avoid breathing dust/fume/gas/mist/vapours/spray. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Toxic

Risk & Safety

Risk Phrases: 23
Toxic by inhalation.
Safety Phrases: 9-36-45-60
Keep container in a well ventilated place. Wear suitable protective clothing. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and/or its container must be disposed of as hazardous waste.
Toxic
TSCA: Yes