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Certificate of Analysis

Perfluorohexanes, 98+%

CAS: 355-42-0 MDL: MFCD00000437  EINECS: 206-585-0
Not regulated for shipping
Alternate Name: Tetradecafluorohexanes


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Chemical Properties

Formula: C6F14  Boiling point: 58-60°
Formula weight: 338.04  Flash point: None
Form: Clear colorless liquid Density: 1.699
Melting point: -4° Refractive Index: 1.2510

Literature References

Non-toxic, non-ozone-depleting alternative to carbon tetrachloride in bromination reactions: Synth. Commun., 25, 1023 (1995).

Reaction medium with substantial capacity to solubilize molecular oxygen as in the photooxidation of alkenes: Synth. Commun., 26, 1861 (1996), or the high yield epoxidation of alkenes in the presence of trimethylacetaldehyde: Synth. Commun., 27, 447 (1997).


85% n-isomer

Other References

Beilstein: 1802113
Harmonized Tariff Code:   2903.39

GHS Hazard and Precautionary Statements

Hazard Statements : H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements : P261-P280-P305+P351+P338-P304+P340-P405-P501A

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Harmful or Irritant

Risk & Safety

Risk Phrases: 36/37/38
Irritating to eyes, respiratory system and skin.
Safety Phrases: 26-37-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves. This material and/or its container must be disposed of as hazardous waste.
RTECS: MO4310000