|Not regulated for shipping|
|Alternate Name:||Bis(p-cymene)diruthenium(II) tetrachloride
Pricing and Availability
|Pricing is currently not available for this product.|
Catalyst for highly stereoselective hydrosilylation of terminal alkynes: Org. Lett., 2, 1887 (2000). Also promotes the aerobic oxidation of benzylic and allylic alcohols to the corresponding aldehydes: Tetrahedron Lett., 41, 7507 (2000).
In the presence of pyrrolidine, catalyzes the 1,4-addition of terminal alkynes to enones to give δ-ynones: Org. Lett., 3, 2089 (2001).
Effective catalyst for dehydration of aldoximes to nitriles: Org. Lett., 3, 4271 (2001).
Verstaile catayst for C-C bond formation by C-H bond activation, for example in the coupling of vinylsilanes with aromatic C-H bonds to give arylethyl silanes: Angew. Chem. Int. Ed., 45, 8232 (2006).
|Harmonized Tariff Code:||2843.90|
GHS Hazard and Precautionary Statements
Causes serious eye damage. Harmful if swallowed. May cause an allergic skin reaction.
Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Dispose of contents/container in accordance with local/regional/national/international regulations.
Risk & Safety
|Harmful if swallowed. Risk of serious damage to eyes. May cause sensitisation by skin contact.|
|Avoid contact with skin. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves and eye/face protection. This material and/or its container must be disposed of as hazardous waste.|