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1-Adamantanol, 99% - CAS 768-95-6 - Formula C10H16O

A10209 768-95-6 1-Adamantanol, 99% 1-Hydroxyadamantane Alfa Aesar

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A10209
1-Adamantanol, 99%

CAS: 768-95-6 MDL: MFCD00074729  EINECS: 212-202-8
Not regulated for shipping
Alternate Name: 1-Hydroxyadamantane

 

Pricing and Availability

Size ($) Price Your Price Quantity Options Availability
10g 27.60 Check Availability Add to Favorites Enter qty and click checkbox
50g 127.00 Check Availability Add to Favorites Enter qty and click checkbox
250g 572.00 Check Availability Add to Favorites Enter qty and click checkbox


Chemical Properties

Formula: C10H16O  Melting point: ca 245° subl.
Formula weight: 152.24  

Literature References

Carboxyl groups of amino acids have been protected as 1-adamantyl esters via the amino acid tosylate and dimethyl sulfite. The group is readily cleaved with TFA under mild conditions: Synthesis, 1355 (1996). Has also been applied in blocking the ß-carboxyl group of aspartic acid in peptide synthesis; the 1-adamantyl ester is prepared using DCC-DMAP: J. Chem. Soc., Perkin 1, 2129 (1988). See also Appendix 6.

Thiol groups may also be protected by formation of the thioether in TFA. Cleavage is by means of Hg(II) salts: Chem. Pharm. Bull., 26, 1576 (1978).

Reaction with Hydrogen fluoride pyridine complex, L17117, gives 1-fluoroadamantane, a general method for conversion of sec- and tert-alcohols to fluoroalkanes: Org. Synth. Coll., 6, 628 (1988).


Other References

Beilstein: 1903952
Harmonized Tariff Code: 2906.19

Risk & Safety

TSCA: No
RTECS: AU4980000