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2-Bromomesitylene, 99% - CAS 576-83-0 - Formula C9H11Br

A12277 576-83-0 2-Bromomesitylene, 99% 2-Bromo-1,3,5-trimethylbenzene 2,4,6-Trimethylbromobenzene Alfa Aesar

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A12277
2-Bromomesitylene, 99%

CAS: 576-83-0 MDL: MFCD00000073  EINECS: 209-405-9
Not regulated for shipping
Alternate Name: 2-Bromo-1,3,5-trimethylbenzene
2,4,6-Trimethylbromobenzene

 

Pricing and Availability

Size ($) Price Your Price Quantity Options Availability
50g 26.40 Check Availability Add to Favorites Enter qty and click checkbox
100g 49.40 Check Availability Add to Favorites Enter qty and click checkbox
250g 118.00 Check Availability Add to Favorites Enter qty and click checkbox
500g 220.00 Check Availability Add to Favorites Enter qty and click checkbox


Chemical Properties

Formula: C9H11Br  Flash point: 96°(204°F)
Formula weight: 199.10  Density: 1.322
Melting point:  Refractive Index: 1.5520
Boiling point: 224-226° Sensitivity: Light Sensitive

Literature References

In the presence of Pd catalysts and a base, aryl bromides can act as oxidizing agents for conversion of alcohols to aldehydes and ketones under mild conditions. While bromobenzene is effective for saturated secondary alcohols: Tetrahedron Lett., 1401 (1979), for unsaturated alcohols, arylation competes and 2-bromomesitylene was found to give superior results: Tetrahedron Lett., 22, 1801 (1981); J. Org. Chem., 48, 1286 (1983). See also: J. Org. Chem., 61, 2918 (1996), for a combined desilylation-oxidation technique.


Other References

Beilstein: 1907245
Harmonized Tariff Code: 2903.99

GHS Hazard and Precautionary Statements

Hazard Statements : H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements : P261-P280-P305+P351+P338-P304+P340-P405-P501A

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Harmful or Irritant

Risk & Safety

Risk Phrases: 36/37/38
Irritating to eyes, respiratory system and skin.
Safety Phrases: 23-26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves.
Irritant
TSCA: Yes