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2-Bromomesitylene, 99% - CAS 576-83-0 - Formula C9H11Br


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A12277
2-Bromomesitylene, 99%

CAS: 576-83-0 MDL: MFCD00000073  EINECS: 209-405-9
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Alternate Name: 2-Bromo-1,3,5-trimethylbenzene
2,4,6-Trimethylbromobenzene

 

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Chemical Properties

Formula: C9H11Br  Flash point: 96°(204°F)
Formula weight: 199.10  Density: 1.322
Melting point:  Refractive Index: 1.5520
Boiling point: 224-226° Sensitivity: Light Sensitive

Literature References

In the presence of Pd catalysts and a base, aryl bromides can act as oxidizing agents for conversion of alcohols to aldehydes and ketones under mild conditions. While bromobenzene is effective for saturated secondary alcohols: Tetrahedron Lett., 1401 (1979), for unsaturated alcohols, arylation competes and 2-bromomesitylene was found to give superior results: Tetrahedron Lett., 22, 1801 (1981); J. Org. Chem., 48, 1286 (1983). See also: J. Org. Chem., 61, 2918 (1996), for a combined desilylation-oxidation technique.


Other References

Beilstein: 1907245
Harmonized Tariff Code:   2903.99

GHS Hazard and Precautionary Statements

Hazard Statements : H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements : P261-P280-P305+P351+P338-P304+P340-P405-P501A

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Harmful or Irritant

Risk & Safety

Risk Phrases: 36/37/38
Irritating to eyes, respiratory system and skin.
Safety Phrases: 23-26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves.
Irritant
TSCA: Yes