|Not regulated for shipping
||C9H11Br || ||Flash point:
||199.10 || ||Density:
||2°|| ||Refractive Index:
||Light Sensitive |
In the presence of Pd catalysts and a base, aryl bromides can act as oxidizing agents for conversion of alcohols to aldehydes and ketones under mild conditions. While bromobenzene is effective for saturated secondary alcohols: Tetrahedron Lett., 1401 (1979), for unsaturated alcohols, arylation competes and 2-bromomesitylene was found to give superior results: Tetrahedron Lett., 22, 1801 (1981); J. Org. Chem., 48, 1286 (1983). See also: J. Org. Chem., 61, 2918 (1996), for a combined desilylation-oxidation technique.
|Harmonized Tariff Code:
GHS Hazard and Precautionary Statements
Hazard Statements : H315-H319-H335
Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements : P261-P280-P305+P351+P338-P304+P340-P405-P501A
Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.
Risk & Safety
|Irritating to eyes, respiratory system and skin.
|In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves.