This site requires that javascript be enabled. Please configure your browser in the tools or configuration section.
Benzyl chloride, 99%, stab. - CAS 100-44-7 - Formula C7H7Cl


MSDS
Region
All
Search

Certificate of Analysis
Lot
Search


A12481
Benzyl chloride, 99%, stab.

CAS: 100-44-7 MDL: MFCD00000889  EINECS: 202-853-6
UN#:UN1738Hazard Class:6.1Packing Group:II
Alternate Name: alpha-Chlorotoluene

 

Pricing and Availability

Size ($) Price Your Price Quantity Options Availability
Please login or select country.


Chemical Properties

Formula: C7H7Cl  Flash point: 73°(163°F)
Formula weight: 126.59  Density: 1.099
Melting point: -43° Refractive Index: 1.5380
Boiling point: 178-180° Solubility: Miscible with alcohol, ether. Insoluble in water

Literature References

Benzyllithium and substituted analogues have proved difficult to generate in a pure state owing to competing Wurtz coupling. Conditions have been described for efficient generation of benzyllithiums from the chlorides using Li naphthalenide in a mixed diethyl ether - THF - petroleum ether solvent system at -95o: J. Chem. Soc., Perkin 1, 185 (1995).

Amidocarbonylation with acetamide and a CO/H2 mixture under pressure, in the presence of Co2(CO)8 catalyst, provides a novel route to N-acetyl-DL-phenylalanine: J. Org. Chem., 61, 1842 (1996).


Other References

Merck: 14,1129
Beilstein: 471308
UN#: UN1738
Harmonized Tariff Code:   2903.99

GHS Hazard and Precautionary Statements

Hazard Statements : H331-H302-H315-H335-H350-H373-H318-H227

Toxic if inhaled. Harmful if swallowed. Causes skin irritation. May cause respiratory irritation. May cause cancer. May cause damage to organs through prolonged or repeated exposure. Causes serious eye damage. Combustible liquid.

Precautionary Statements : P210-P260-P261-P305+P351+P338-P405-P501A

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Avoid breathing dust/fume/gas/mist/vapours/spray. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

CorrosiveToxicHealth Hazard

Risk & Safety

Risk Phrases: 45-22-23-37/38-41-48/22
May cause cancer. Harmful if swallowed. Toxic by inhalation. Irritating to respiratory system and skin. Risk of serious damage to eyes. Harmful: danger of serious damage to health by prolonged exposure if swallowed.
Safety Phrases: 53-45
Avoid exposure - obtain special instructions before use. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
Toxic
TSCA: Yes
RTECS: XS8925000