Benzyl chloride, 99%, stab.
|UN#:||UN1738||Hazard Class:||6.1||Packing Group:||II
Pricing and Availability
||C7H7Cl || ||Flash point:
||126.59 || ||Density:
||-43°|| ||Refractive Index:
||Miscible with alcohol, ether. Insoluble in water|
Benzyllithium and substituted analogues have proved difficult to generate in a pure state owing to competing Wurtz coupling. Conditions have been described for efficient generation of benzyllithiums from the chlorides using Li naphthalenide in a mixed diethyl ether - THF - petroleum ether solvent system at -95o: J. Chem. Soc., Perkin 1, 185 (1995).
Amidocarbonylation with acetamide and a CO/H2 mixture under pressure, in the presence of Co2(CO)8 catalyst, provides a novel route to N-acetyl-DL-phenylalanine: J. Org. Chem., 61, 1842 (1996).
|Harmonized Tariff Code:
GHS Hazard and Precautionary Statements
Hazard Statements : H331-H302-H315-H335-H350-H373-H318-H227
Toxic if inhaled. Harmful if swallowed. Causes skin irritation. May cause respiratory irritation. May cause cancer. May cause damage to organs through prolonged or repeated exposure. Causes serious eye damage. Combustible liquid.
Precautionary Statements : P210-P260-P261-P305+P351+P338-P405-P501A
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Avoid breathing dust/fume/gas/mist/vapours/spray. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.
Risk & Safety
|May cause cancer. Harmful if swallowed. Toxic by inhalation. Irritating to respiratory system and skin. Risk of serious damage to eyes. Harmful: danger of serious damage to health by prolonged exposure if swallowed.
|Avoid exposure - obtain special instructions before use. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).