A12481

Benzyl chloride, 99%, stab.

CAS Number 100-44-7 Synonyms
  • alpha-Chlorotoluene

 
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Benzyl chloride, 99%, stab.

MDL: MFCD00000889
EINECS: 202-853-6

Chemical Properties

Formula: C7H7Cl  Flash point: 73°(163°F)
Formula weight: 126.59  Density: 1.099
Melting point: -43° Refractive Index: 1.5380
Boiling point: 178-180° Solubility: Miscible with alcohol, ether. Insoluble in water

Literature References

Benzyllithium and substituted analogues have proved difficult to generate in a pure state owing to competing Wurtz coupling. Conditions have been described for efficient generation of benzyllithiums from the chlorides using Li naphthalenide in a mixed diethyl ether - THF - petroleum ether solvent system at -95o: J. Chem. Soc., Perkin 1, 185 (1995).

Amidocarbonylation with acetamide and a CO/H2 mixture under pressure, in the presence of Co2(CO)8 catalyst, provides a novel route to N-acetyl-DL-phenylalanine: J. Org. Chem., 61, 1842 (1996).

GHS Hazard and Precautionary Statements

Hazard Statements : H301-H330-H335-H350-H373-H314-H318-H227

Toxic if swallowed. Fatal if inhaled. May cause respiratory irritation. May cause cancer. May cause damage to organs through prolonged or repeated exposure. Causes severe skin burns and eye damage. Causes serious eye damage. Combustible liquid.

Precautionary Statements : P210-P301+P310-P303+P361+P353-P304+P340-P305+P351+P338-P320-P330-P405-P501A

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment is urgent (see label). Rinse mouth. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

CorrosiveToxicHealth Hazard

Other References

Merck: 14,1129
Beilstein: 471308
UN#: UN1738
Hazard Class: 6.1
Packing Group: II
Harmonized Tariff Code: 2903.99
TSCA: Yes
RTECS: XS8925000
Benzyl chloride, 99%, stab. - CAS 100-44-7 - Formula C7H7Cl

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