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trans-Cinnamaldehyde, 98+% - CAS 14371-10-9 - Formula C9H8O


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A14689
trans-Cinnamaldehyde, 98+%

CAS: 14371-10-9 MDL: MFCD00007000  
Not regulated for shipping
Alternate Name: trans-3-Phenylacrolein

 

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Chemical Properties

Formula: C9H8O  Flash point: 131°(268°F)
Formula weight: 132.16  Density: 1.050
Melting point: -8° Refractive Index: 1.6220
Boiling point: 250-252° Sensitivity: Air Sensitive

Literature References

For details of the 1,2-addition of a functionalized Zn-Cu organometallic RCu(CN)ZnI to give an allylic alcohol, see; Org. Synth. Coll., 9, 502 (1998).

For reaction with 1,2-Ethanedithiol, L12865 to give the dithiolane, followed by coupling with trimethylsilylmethyl magnesium chloride, catalyzed by Dichlorobis(triphenyl­phosphine)­nickel(II)­, 13930, as an example of Ni catalyzed coupling of dithioacetals with Grignards, see: J. Org. Chem., 53, 5582 (1988); Org. Synth. Coll., 9, 727 (1998):


Other References

Merck: 14,2297
Beilstein: 1071571
Harmonized Tariff Code:   2912.29

GHS Hazard and Precautionary Statements

Hazard Statements : H315-H319-H317-H303-H313

Causes skin irritation. Causes serious eye irritation. May cause an allergic skin reaction. May be harmful if swallowed. May be harmful in contact with skin.

Precautionary Statements : P280G-P262-P305+P351+P338

Wear protective gloves. Do not get in eyes, on skin, or on clothing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Harmful or Irritant

Risk & Safety

Risk Phrases: 36/38-43
Irritating to eyes and skin. May cause sensitisation by skin contact.
Safety Phrases: 24-26-37
Avoid contact with skin. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves.
Irritant
TSCA: No
RTECS: GD6475000