|Not regulated for shipping
||C9H8O || ||Flash point:
||132.16 || ||Density:
||-8°|| ||Refractive Index:
||Air Sensitive |
For details of the 1,2-addition of a functionalized Zn-Cu organometallic RCu(CN)ZnI to give an allylic alcohol, see; Org. Synth. Coll., 9, 502 (1998).
For reaction with 1,2-Ethanedithiol, L12865 to give the dithiolane, followed by coupling with trimethylsilylmethyl magnesium chloride, catalyzed by Dichlorobis(triphenylphosphine)nickel(II), 13930, as an example of Ni catalyzed coupling of dithioacetals with Grignards, see: J. Org. Chem., 53, 5582 (1988); Org. Synth. Coll., 9, 727 (1998):
|Harmonized Tariff Code:
GHS Hazard and Precautionary Statements
Hazard Statements : H315-H319-H317-H303-H313
Causes skin irritation. Causes serious eye irritation. May cause an allergic skin reaction. May be harmful if swallowed. May be harmful in contact with skin.
Precautionary Statements : P280G-P262-P305+P351+P338
Wear protective gloves. Do not get in eyes, on skin, or on clothing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Risk & Safety
|Irritating to eyes and skin. May cause sensitisation by skin contact.
|Avoid contact with skin. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves.