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4-Nitrobenzyl chloride, 99% - CAS 100-14-1 - Formula C7H6ClNO2

A15749 100-14-1 4-Nitrobenzyl chloride, 99% alpha-Chloro-4-nitrotoluene Alfa Aesar


Certificate of Analysis

4-Nitrobenzyl chloride, 99%

CAS: 100-14-1 MDL: MFCD00007374  EINECS: 202-822-7
UN#:UN3261Hazard Class:8Packing Group:II
Alternate Name: alpha-Chloro-4-nitrotoluene


Pricing and Availability

Size ($) Price Your Price Quantity Options Availability
10g 22.00 Check Availability Add to Favorites Enter qty and click checkbox
50g 57.40 Check Availability Add to Favorites Enter qty and click checkbox
250g 229.00 Check Availability Add to Favorites Enter qty and click checkbox

Chemical Properties

Formula: C7H6ClNO2  Melting point: 70-74°
Formula weight: 171.58  

Literature References

Reagent for carboxyl protection in peptide synthesis. Derivatives are stable to HBr, but cleaved by hydrogenolysis: J. Am. Chem. Soc., 81, 5691 (1959); J. Chem. Soc., 4922 (1965). See also 4-Nitrobenzyl­ alcohol, A15742, 4-Nitrobenzyl­ bromide, A15236, and Appendix 6.

Has also been used for protection of the thiol group: J. Org. Chem., 37, 3550 (1972); J. Chem. Soc., Chem. Commun., 12 (1974).

Other References

Beilstein: 387187
UN#: UN3261
Harmonized Tariff Code: 2904.90

GHS Hazard and Precautionary Statements

Hazard Statements : H301-H332-H314-H318-H341

Toxic if swallowed. Harmful if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage. Suspected of causing genetic defects.

Precautionary Statements : P260-P301+P310-P303+P361+P353-P305+P351+P338-P405-P501A

Do not breathe dust/fume/gas/mist/vapours/spray. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

CorrosiveToxicHealth Hazard

Risk & Safety

Risk Phrases: 20/22-34-68
Harmful by inhalation and if swallowed. Causes burns. Possible risk of irreversible effects
Safety Phrases: 26-36/37/39-45
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
Harmful Corrosive
RTECS: XS9093000