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A16203 6046-93-1 Copper(II) acetate monohydrate, 98+% Acetic acid copper(II) salt Cupric acetate Alfa Aesar

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A16203
Copper(II) acetate monohydrate, 98+%

CAS: 6046-93-1 MDL: MFCD00149570  EINECS: 205-553-3
UN#:UN3077Hazard Class:9Packing Group:III
Alternate Name: Acetic acid copper(II) salt
Cupric acetate

 

Pricing and Availability

Size ($) Price Your Price Quantity Options Availability
250g 33.30 Check Availability Add to Favorites Enter qty and click checkbox
1000g 98.70 Check Availability Add to Favorites Enter qty and click checkbox
5000g 390.00 Check Availability Add to Favorites Enter qty and click checkbox


Chemical Properties

Formula: C4H6CuO4•H2O  Melting point: 115°
Formula weight: 199.65 (181.64anhy)  Density: 1.882

Literature References

Used in formation of Cu chelates of ß-dicarbonyl compounds as a means of purification, see, e.g.: Org. Synth. Coll., 3, 16, 292, 390 (1955).

For use in the Eglinton (modified Glaser) coupling of terminal alkynes, see: Org. Synth. Coll., 5, 517 (1973); for intramolecular example in the synthesis of [18]annulene, see: Org. Synth. Coll., 6, 68 (1988).

Useful catalyst for the Michael reaction giving increased yields and absence of side-reactions: Gazz. Chim. Ital., 114, 417 (1984).

Promotes Ullmann-type C-O and C-N coupling reactions of arylboronic acids with phenols, amines and various other nitogen derivatives: Tetrahedron Lett., 39, 2933, 2937, 2941, 7979 (1998). Similar coupling reactions with thiols to give thioethers have also been reported: Org. Lett., 2, 2019 (2000).


Other References

Merck: 14,2624
UN#: UN3077
Harmonized Tariff Code: 2915.29

GHS Hazard and Precautionary Statements

Hazard Statements : H400-H410-H302-H315-H319-H335

Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects. Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements : P261-P280-P305+P351+P338-P304+P340-P405-P501A

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Harmful or IrritantDangerous for the environment

Risk & Safety

Risk Phrases: 22-36/37/38-50/53
Harmful if swallowed. Irritating to eyes, respiratory system and skin. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Phrases: 26-36/37-57-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing and gloves. Use appropriate containment to avoid environmental contamination. This material and/or its container must be disposed of as hazardous waste.
Harmful Dangerous for the environment
TSCA: Yes
RTECS: AG3500000