|UN#:||UN2386||Hazard Class:||3||Packing Group:||II
||C7H15N || ||Flash point:
||113.20 || ||Density:
||-20°|| ||Refractive Index:
Hindered, non-nucleophilic base. Preferred base for enantioselective crossed aldol condensations of Sn enolates: Tetrahedron, 40, 1381 (1984). Also found to give excellent results in the formation of anhydrides using Bis(2-oxo-3-oxazolidinyl)phosphinic chloride, L08775: Synthesis, 616 (1981). Has been used in peptide synthesis via pivaloyl mixed anhydrides: Coll. Czech. Chem. Commun., 27, 1273 (1962).
|Harmonized Tariff Code:
GHS Hazard and Precautionary Statements
Hazard Statements : H225-H314-H318
Highly flammable liquid and vapour. Causes severe skin burns and eye damage. Causes serious eye damage.
Precautionary Statements : P210-P260-P303+P361+P353-P305+P351+P338-P405-P501A
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.
Risk & Safety
|Flammable. Causes burns.
|Keep container tightly closed. When using do not eat or drink. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Take precautionary measures against static discharges. Wear suitable protective clothing, gloves and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and/or its container must be disposed of as hazardous waste.