2,6-Difluorobenzyl bromide, 97+%

CAS Number 85118-00-9 Synonyms
  • alpha-Bromo-2,6-difluorotoluene

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2,6-Difluorobenzyl bromide, 97+%

MDL: MFCD00000329
EINECS: 285-652-6

Chemical Properties

Formula: C7H5BrF2  Flash point: >110°(230°F)
Formula weight: 207.02  Density: 1.600
Melting point: 49-53° 

Literature References

Reagent for protection of alcohols as 2,6-difluorobenzyl ethers which can be formed in the presence of Ba(OH)2 in DMF: Helv. Chim. Acta, 79, 1159 (1996). Unlike benzyl ethers, these are stable during cationic reactions. They can be cleaved by dissolving metal reduction (Ca/NH3): Chimia, 329 (1991).

GHS Hazard and Precautionary Statements

Hazard Statements : H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements : P260-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501A

Do not breathe dust/fume/gas/mist/vapours/spray. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.


Other References

Beilstein: 2083943
UN#: UN1759
Hazard Class: 8
Packing Group: III
Harmonized Tariff Code: 2903.99
2,6-Difluorobenzyl bromide, 97+% - CAS 85118-00-9 - Formula C7H5BrF2


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