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Certificate of Analysis

Tribromofluoromethane, 99%, stab. with copper

CAS: 353-54-8 MDL: MFCD00000366  EINECS: 206-535-8
Not regulated for shipping
Alternate Name: Fluorotribromomethane
Halon 1103


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Chemical Properties

Formula: CBr3F  Flash point: None
Formula weight: 270.72  Density: 2.765
Melting point: -74° Refractive Index: 1.5255
Boiling point: 106-107° 

Literature References

For generation and carbonyl addition of the thermally labile species dibromofluoromethyllithium with n-BuLi at -130o, see: Synlett, 987 (1995).

Undergoes Pd-catalyzed addition to olefins to give 1,1,3-tribromo-1-fluoroalkanes: Tetrahedron Lett., 47, 9245 (2006).

Other References

Beilstein: 1732796
Harmonized Tariff Code:   2903.78

GHS Hazard and Precautionary Statements

Hazard Statements : H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements : P280G-P305+P351+P338

Wear protective gloves. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Harmful or Irritant

Risk & Safety

Risk Phrases: 36/37/38
Irritating to eyes, respiratory system and skin.
Safety Phrases: 26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves.