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B22405 764-35-2 2-Hexyne, 98+% Alfa Aesar

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B22405
2-Hexyne, 98+%

CAS: 764-35-2 MDL: MFCD00009470  EINECS: 212-117-6
UN#:UN3295Hazard Class:3Packing Group:II

 

Pricing and Availability

Size ($) Price Your Price Quantity Options Availability
10g 40.20 Check Availability Add to Favorites Enter qty and click checkbox
50g 174.00 Check Availability Add to Favorites Enter qty and click checkbox


Chemical Properties

Formula: CH3(CH2)2C≡CCH3  Flash point: -10°(14°F)
Formula weight: 82.15  Density: 0.736
Melting point: -90° Refractive Index: 1.4140
Boiling point: 84-86° 

Literature References

2-Alkynes are metallated almost exclusively at the terminal position by t-BuLi + TMEDA in ether. Subsequent reaction with, e.g. TMS chloride gives propargylic silanes: Synthesis, 111 (1984).

On heating under pressure with norbornene and CO in the presence of Dodecacarbonyl­triruthenium, 10507, alkynes undergo aromatization to give condensed hydroquinones: Organometallics, 17, 766 (1998):


Other References

Beilstein: 1731542
UN#: UN3295
Harmonized Tariff Code: 2901.29

GHS Hazard and Precautionary Statements

Hazard Statements : H225-H304-H315-H319-H335

Highly flammable liquid and vapour. May be fatal if swallowed and enters airways. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements : P210-P301+P310-P303+P361+P353-P305+P351+P338-P405-P501A

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

FlammableHarmful or IrritantHealth Hazard

Risk & Safety

Risk Phrases: 11-36/37/38-65
Flammable. Irritating to eyes, respiratory system and skin. Harmful: May cause lung damage if swallowed.
Safety Phrases: 9-16-26-29-33-37-62
Keep container in a well ventilated place. Keep away from sources of ignition - No Smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Do not empty into drains. Take precautionary measures against static discharges. Wear suitable gloves. If swallowed, do not induce vomiting: seek medical advice immediately & show this container or label.
Harmful Highly Flammable
TSCA: No