B24952

Benzyltriethylammonium borohydride, 96%

CAS Number 85874-45-9 Synonyms
  • Benzyltriethylammonium tetrahydridoborate

 
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Benzyltriethylammonium borohydride, 96%

MDL: MFCD00191785

Chemical Properties

Formula: C13H26BN  Melting point: ca 146° dec.
Formula weight: 207.17  Sensitivity: Moisture Sensitive

Literature References

In the presence of TMS chloride or TiCl4, converts alkenes to the anti-Markovnikov alcohols in good yield: J. Chem. Soc., Chem. Commun., 903 (1989); Tetrahedron Lett., 34, 171 (1993).

In combination with TMS chloride, selectively reduces carboxylic acids to alcohols; esters, lactones, nitro- and chloro-substituents are unaffected: Synth. Commun., 20, 907 (1990). For example and reaction scheme, see 4-Nitrobenzoic acid, A14738. See also Tetra-n-butyl­ammonium borohydride, A17494.

GHS Hazard and Precautionary Statements

Hazard Statements : H261-H314-H318-H302

In contact with water releases flammable gas. Causes severe skin burns and eye damage. Causes serious eye damage. Harmful if swallowed.

Precautionary Statements : P280-P303+P361+P353-P305+P351+P338-P310-P370+P378I-P402+P404

Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. In case of fire: Use for extinction: Fire-extinguishing powder. Store in a dry place. Store in a closed container.

FlammableCorrosiveHarmful or Irritant

Other References

UN#: UN3131
Hazard Class: 4.3
Packing Group: II
Harmonized Tariff Code: 2923.90
TSCA: No

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