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B24952 85874-45-9 Benzyltriethylammonium borohydride, 96% Benzyltriethylammonium tetrahydridoborate Alfa Aesar

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B24952
Benzyltriethylammonium borohydride, 96%

CAS: 85874-45-9 MDL: MFCD00191785  
UN#:UN3131Hazard Class:4.3Packing Group:II
Alternate Name: Benzyltriethylammonium tetrahydridoborate

 

Pricing and Availability

Size ($) Price Your Price Quantity Options Availability
5g 36.80 Check Availability Add to Favorites Enter qty and click checkbox
25g 151.00 Check Availability Add to Favorites Enter qty and click checkbox
100g 665.00 Check Availability Add to Favorites Enter qty and click checkbox


Chemical Properties

Formula: C13H26BN  Melting point: ca 146° dec.
Formula weight: 207.17  Sensitivity: Moisture Sensitive

Literature References

In the presence of TMS chloride or TiCl4, converts alkenes to the anti-Markovnikov alcohols in good yield: J. Chem. Soc., Chem. Commun., 903 (1989); Tetrahedron Lett., 34, 171 (1993).

In combination with TMS chloride, selectively reduces carboxylic acids to alcohols; esters, lactones, nitro- and chloro-substituents are unaffected: Synth. Commun., 20, 907 (1990). For example and reaction scheme, see 4-Nitrobenzoic acid, A14738. See also Tetra-n-butyl­ammonium borohydride, A17494.


Other References

UN#: UN3131
Harmonized Tariff Code: 2923.90

GHS Hazard and Precautionary Statements

Hazard Statements : H261-H314-H318-H302

In contact with water releases flammable gas. Causes severe skin burns and eye damage. Causes serious eye damage. Harmful if swallowed.

Precautionary Statements : P280-P303+P361+P353-P305+P351+P338-P310-P370+P378I-P402+P404

Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. In case of fire: Use for extinction: Fire-extinguishing powder. Store in a dry place. Store in a closed container.

FlammableCorrosiveHarmful or Irritant

Risk & Safety

Risk Phrases: 15-22-34
Contact with water liberates highly flammable gases. Harmful if swallowed. Causes burns.
Safety Phrases: 7/8-26-36/37/39-43-45
Keep container tightly closed and dry. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
Harmful Corrosive Highly Flammable
TSCA: No