B25085

Dimethylaminoacetonitrile, 98%

CAS Number 926-64-7

 
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Dimethylaminoacetonitrile, 98%

MDL: MFCD00001890
EINECS: 213-140-4

Chemical Properties

Formula: C4H8N2  Flash point: 36°(96°F)
Formula weight: 84.12  Density: 0.863
Boiling point: 137-138° Refractive Index: 1.4100

Literature References

Formyl anion equivalent. Self-condensation was found to compete with alkylation in the Stork LDA procedure, but the molecule was successfully used to introduce a formyl group by SN2' alkylation in the presence of K2CO3, in a synthesis of -cyclocitral: Tetrahedron Lett., 25, 3457 (1984):

For a review of the use of ɑ-dialkylaminonitriles as acyl anion equivalents, see: Tetrahedron, 39, 3207 (1983).

GHS Hazard and Precautionary Statements

Hazard Statements : H300-H310-H319-H226

Fatal if swallowed. Fatal in contact with skin. Causes serious eye irritation. Flammable liquid and vapour.

Precautionary Statements : P260-P280H-P305+P351+P338-P309-P310-P302+P352

Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/clothing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or if you feel unwell: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN: Wash with plenty of soap and water.

FlammableToxic

Other References

Beilstein: 1735677
UN#: UN2378
Hazard Class: 3
Packing Group: II
Harmonized Tariff Code: 2926.90
TSCA: No
RTECS: AL9450000

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