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L01723 3561-67-9 Bis(phenylthio)methane, 98+% Formaldehyde diphenyl mercapatal Alfa Aesar

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L01723
Bis(phenylthio)methane, 98+%

CAS: 3561-67-9 MDL: MFCD00003067  EINECS: 222-624-4
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Alternate Name: Formaldehyde diphenyl mercapatal

 

Pricing and Availability

Size ($) Price Your Price Quantity Options Availability
5g 25.30 Check Availability Add to Favorites Enter qty and click checkbox
25g 81.40 Check Availability Add to Favorites Enter qty and click checkbox


Chemical Properties

Formula: C13H12S2  Melting point: 36-38°
Formula weight: 232.36  Boiling point: 194°/8mm

Literature References

Acyl anion equivalent, compare 1,3-Dithiane, A10505. Can be metallated, e.g. with n-BuLi. Dimetallation requires a metal complexing agent, e.g. TMEDA, allowing dialkylation: Tetrahedron Lett., 21, 4763 (1980).

The products of addition of the lithio-derivative to aldehydes and ketones undergo a pinacol-type rearrangement with CuOTf, with insertion of a one-carbon unit adjacent to the carbonyl group: J. Am. Chem. Soc., 97, 4749 (1975); see also: Org. Synth. Coll., 6, 737 (1988). An alternative method utilizes an alkyllithium to effect a carbenoid rearrangement, which has been applied to ring expansion: Tetrahedron Lett., 28, 20 (1987):


Other References

Beilstein: 1874146
Harmonized Tariff Code: 2930.90

Risk & Safety

TSCA: No