L01723

Bis(phenylthio)methane, 98+%

CAS Number 3561-67-9 Synonyms
  • Formaldehyde diphenyl mercapatal
Not regulated for shipping

 
Size Price ($) Your Price Quantity Options Availability
5g 25.30 Check Availability Add to Favorites Enter qty and click ?
25g 81.40 Check Availability Add to Favorites Enter qty and click ?

Bis(phenylthio)methane, 98+%

MDL: MFCD00003067
EINECS: 222-624-4

Chemical Properties

Formula: C13H12S2  Melting point: 36-38°
Formula weight: 232.36  Boiling point: 194°/8mm

Literature References

Acyl anion equivalent, compare 1,3-Dithiane, A10505. Can be metallated, e.g. with n-BuLi. Dimetallation requires a metal complexing agent, e.g. TMEDA, allowing dialkylation: Tetrahedron Lett., 21, 4763 (1980).

The products of addition of the lithio-derivative to aldehydes and ketones undergo a pinacol-type rearrangement with CuOTf, with insertion of a one-carbon unit adjacent to the carbonyl group: J. Am. Chem. Soc., 97, 4749 (1975); see also: Org. Synth. Coll., 6, 737 (1988). An alternative method utilizes an alkyllithium to effect a carbenoid rearrangement, which has been applied to ring expansion: Tetrahedron Lett., 28, 20 (1987):

Other References

Beilstein: 1874146
Harmonized Tariff Code: 2930.90
TSCA: No

Recommended

  • A10505

    1,3-Dithiane, 98%
  • A12535

    Trimethylsilyl trifluoromethanesulfonate, 99%
  • A15331

    4-Methoxyphenyl isothiocyanate, 98%
  • L06233

    n-Dodecyl gallate, 98%

Recently Viewed

    Chemicals

    Life Science

    Metals & Materials

    Catalysts

    Analytical & Labware