L04558

Dimethylphenylsilane, 97%

CAS Number 766-77-8 Synonyms
  • Phenyldimethylsilane

 
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Dimethylphenylsilane, 97%

MDL: MFCD00008257
EINECS: 212-170-5

Chemical Properties

Formula: C8H12Si  Flash point: 35°(95°F)
Formula weight: 136.27  Density: 0.879
Melting point: -124° Refractive Index: 1.4970
Boiling point: 156-157° 

Literature References

Silylation of hydroxyl groups gives DMPS ethers under very mild conditions using TBAF catalysis: Tetrahedron Lett., 35, 8413 (1994). See also Chlorodimethyl­phenyl­silane, A15638 and Appendix 4.

Reagent for the highly diastereoselective reduction of ketones to alcohols, in the presence of TBAF or TFA: J. Am. Chem. Soc., 106, 4629 (1984); J. Org. Chem., 53, 5415 (1988):

For an example of reduction of a ß-keto amide to a ß-hydroxy amide, see: Org. Synth. Coll., 8, 326 (1993).

For a review of silane reductions, see: Org. Prep. Proced. Int., 12, 13 (1980).

GHS Hazard and Precautionary Statements

Hazard Statements : H226

Flammable liquid and vapour.

Precautionary Statements : P210-P280-P240-P303+P361+P353-P403+P235-P501A

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves/protective clothing/eye protection/face protection. Ground/bond container and receiving equipment. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Store in a well-ventilated place. Keep cool. Dispose of contents/container in accordance with local/regional/national/international regulations.

Flammable

Other References

Beilstein: 2204906
UN#: UN1993
Hazard Class: 3
Packing Group: III
Harmonized Tariff Code: 2931.90
TSCA: Yes
Dimethylphenylsilane, 97% - CAS 766-77-8 - Formula C8H12Si

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