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Dimethylphenylsilane, 97% - CAS 766-77-8 - Formula C8H12Si

L04558 766-77-8 Dimethylphenylsilane, 97% Phenyldimethylsilane Alfa Aesar

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L04558
Dimethylphenylsilane, 97%

CAS: 766-77-8 MDL: MFCD00008257  EINECS: 212-170-5
UN#:UN1993Hazard Class:3Packing Group:III
Alternate Name: Phenyldimethylsilane

 

Pricing and Availability

Size ($) Price Your Price Quantity Options Availability
10g 38.90 Check Availability Add to Favorites Enter qty and click checkbox
50g 116.00 Check Availability Add to Favorites Enter qty and click checkbox


Chemical Properties

Formula: C8H12Si  Flash point: 35°(95°F)
Formula weight: 136.27  Density: 0.879
Melting point: -124° Refractive Index: 1.4970
Boiling point: 156-157° 

Literature References

Silylation of hydroxyl groups gives DMPS ethers under very mild conditions using TBAF catalysis: Tetrahedron Lett., 35, 8413 (1994). See also Chlorodimethyl­phenyl­silane, A15638 and Appendix 4.

Reagent for the highly diastereoselective reduction of ketones to alcohols, in the presence of TBAF or TFA: J. Am. Chem. Soc., 106, 4629 (1984); J. Org. Chem., 53, 5415 (1988):

For an example of reduction of a ß-keto amide to a ß-hydroxy amide, see: Org. Synth. Coll., 8, 326 (1993).

For a review of silane reductions, see: Org. Prep. Proced. Int., 12, 13 (1980).


Other References

Beilstein: 2204906
UN#: UN1993
Harmonized Tariff Code: 2931.90

GHS Hazard and Precautionary Statements

Hazard Statements : H226

Flammable liquid and vapour.

Precautionary Statements : P210-P280-P240-P303+P361+P353-P403+P235-P501A

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves/protective clothing/eye protection/face protection. Ground/bond container and receiving equipment. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Store in a well-ventilated place. Keep cool. Dispose of contents/container in accordance with local/regional/national/international regulations.

Flammable

Risk & Safety

Risk Phrases: 10
Flammable.
TSCA: Yes