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Tri(2-furyl)phosphine, 97% - CAS 5518-52-5 - Formula C12H9O3P

L13329 5518-52-5 Tri(2-furyl)phosphine, 97% Tris(2-furyl)phosphine Alfa Aesar

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L13329
Tri(2-furyl)phosphine, 97%

CAS: 5518-52-5 MDL: MFCD00151857  EINECS: 000-000-0
Not regulated for shipping
Alternate Name: Tris(2-furyl)phosphine

 

Pricing and Availability

Size ($) Price Your Price Quantity Options Availability
250mg 27.60 Check Availability Add to Favorites Enter qty and click checkbox
1g 65.40 Check Availability Add to Favorites Enter qty and click checkbox
5g 253.00 Check Availability Add to Favorites Enter qty and click checkbox


Chemical Properties

Formula: C12H9O3P  Melting point: 59-64°
Formula weight: 232.18  Boiling point: 136°/4mm

Literature References

Best ligand for Pd-catalyzed coupling of 5-iodouracil and unsaturated tributylstannanes: Synlett, 157 (1991).

Large rate enhancements (10 2 -10 3 ) over triphenylphosphine are observed in Pd-catalyzed coupling of olefinic stannanes and electrophiles: J. Am. Chem. Soc ., 113, 9585 (1991).

In a study of Pd-catalyzed coupling reactions in supercritical CO 2, this ligand was among the best tried in both the Stille and Heck reactions, giving much superior results to e.g. triphenyl- or tri(o-tolyl)phosphine: Chem. Commun., 1397 (1998). See also Tris[3,5-bis(trifluoromethyl)­phenyl­]phosphine, L06941.


Other References

Beilstein: 1577564
Harmonized Tariff Code: 2932.19

GHS Hazard and Precautionary Statements

Hazard Statements : H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements : P261-P280-P305+P351+P338-P304+P340-P405-P501A

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Harmful or Irritant

Risk & Safety

Risk Phrases: 36/37/38
Irritating to eyes, respiratory system and skin.
Safety Phrases: 26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves.
Irritant
TSCA: No