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Tris(dibenzylideneacetone)dipalladium(0) chloroform adduct, 98% - CAS 52522-40-4 - Formula C51H42O3Pd2•CHCl3


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L15980
Tris(dibenzylideneacetone)dipalladium(0) chloroform adduct, 98%

CAS: 52522-40-4 MDL: MFCD00075479  
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Alternate Name: Dipalladiumtris(dibenzylideneacetone) chloroform adduct

 

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Chemical Properties

Formula: C51H42O3Pd2•CHCl3  Melting point: 131-135°
Formula weight: 1035.12  

Literature References

Phosphine-free Pd(0) catalyst. Catalyzes the addition of arylboronic acids to aldehydes, affording secondary alcohols. No reaction was observed in the absence of chloroform: Org. Lett., 7, 4153 (2005).


Other References

Harmonized Tariff Code:   2843.90

GHS Hazard and Precautionary Statements

Hazard Statements : H301-H351-H373

Toxic if swallowed. Suspected of causing cancer. May cause damage to organs through prolonged or repeated exposure.

Precautionary Statements : P260-P281-P301+P310-P308+P313-P405-P501A

Do not breathe dust/fume/gas/mist/vapours/spray. Use personal protective equipment as required. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF exposed or concerned: Get medical advice/attention. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

ToxicHealth Hazard

Risk & Safety

Risk Phrases: 22-40-48/20/22
Harmful if swallowed. Possible risk of irreversible effects. Harmful: danger of serious damage to health by prolonged exposure through inhalation and if swallowed.
Safety Phrases: 36/37
Wear suitable protective clothing and gloves.
Harmful
TSCA: No