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15337-84-5 - trans-Dichlorobis(diethylsulfide)platinum(II), Pt 43.7% - 10484 - Alfa Aesar

10484 trans-Dichlorobis(diethylsulfide)platinum(II), Pt 43.7%

CAS-Nummer
15337-84-5
Synonyme

Größe Preis ($) Menge Verfügbarkeit
1g 102,00
5g 447,00
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trans-Dichlorobis(diethylsulfide)platinum(II), Pt 43.7%

MDL
MFCD00050943
EINECS
239-373-1

Chemische Eigenschaften

Formel
Pt[(C2H5)2S]2Cl2
Molmasse
446.37
Form
Crystalline
Löslichkeit
Soluble in acetone, alcohol, ethyl acetate and benzene

Anwendungen

It is used in Hydrosilylation. Platinum(II) complexes of diethylsulfide are convenient and versatile precursor for the preparation of a variety of organoplatinum(II) derivatives.

Bemerkungen

Literaturverweise

Tobita, H.; Habazaki, H.; Ogino, H. Fast Cis-Trans Isomerization of Square-Planar Bis(diethyl sulfide)platinum(II) Complexes. Reaction of cis- Dichlorobis(diethylsulfide)platinum(II) with Mesityllithium. Bull. Chem. Soc. 1987, 60, 797-799.

Momeni, B. Z.; Baleh, L. J.; Hamzeh, S.; Rominger, F. Insertion of SnCl2 into Pt-Cl bonds: synthesis and characterization of four- and five-coordinate trichlorostannylplatinum(II) complexes. J. Coord. Chem. 2007, 60 (3), 285-293.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Harmonized Tariff Code
2843.90
TSCA
No

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