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As a catalyst of choice in hydrogenation, hydrosilation, carbonylation, oxidation, elimination, reduction, allyl aceate isomerization, dimerization of 1,3-dienes, and C-C bond formation such as Negishi coupling, Suzuki coupling, Kumada coupling, Sonogashira coupling, Heck coupling and Sonogashira-Hagihara coupling reactions. Used in the preparation of tetrakis(triphenylphosphine)palladium, condensed heterocycles such as furoquinolines, diphenylacetylenes, and several other compounds.
Talhami, A.; Penn, L.; Jaber, N.; Hamza, K.; Blum, J. Sol-gel Entrapped Dichlorobis(triphenylphosphine)palladium as an Efficient Recyclable Catalyst for the Cross-coupling of Aryl Halides with Indium- and related Alkylating Reagents. Appl. Catal., A 2006, 312, 115-119.
Evans, P. J.; Darzi, E. R.; Jasti, R. Efficient room-temperature synthesis of a highly strained carbon nanohoop fragment of buckminsterfullerene. Nat. Chem. 2014, 6, 404-408.
Abe, Y.; Aoki, T.; Jia, H.; Hadano, S.; Namikoshi, T.; Kakihana, Y.; Liu, L.; Zang, Y.; Teraguchi, M.; Kaneko, T. Synthesis of Stable and Soluble One-Handed Helical Homopoly(substituted acetylene)s without the Coexistence of Any Other Chiral Moieties via Two-Step Polymer Reactions in Membrane State: Molecular Design of the Starting Monomer. Molecules 2012, 17, 433-451.