Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

12107-56-1 - Dichloro(1,5-cyclooctadiene)palladium(II), Pd 36.7% - 10493 - Alfa Aesar

10493 Dichloro(1,5-cyclooctadiene)palladium(II), Pd 36.7%

CAS-Nummer
12107-56-1
Synonyme

Größe Preis ($) Menge Verfügbarkeit
1g 76,58
5g 256,08
Zum Warenkorb hinzufügen Zur Angebotsanfrage hinzufügen Artikel anzeigen

Dichloro(1,5-cyclooctadiene)palladium(II), Pd 36.7%

MDL
MFCD00012412
EINECS
235-161-8

Chemische Eigenschaften

Formel
C8H12Cl2Pd
Molmasse
285.49
Form
Crystalline
Sensitivität
Hygroscopic
Löslichkeit
Soluble in dichloromethane

Anwendungen

Dichloro(1,5-cyclooctadiene)palladium(II) is used as catalyst for C-C bond and C-N formation, used in Heck coupling of alkynes with alkenes, Suzuki cross-coupling of aryl bromides , allylic substitution of oximes with allylic acetate and methoxycarbonylation of iodobenzene.

Bemerkungen

Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. It is sensitive to air. It is hygroscopic in nature. Incompatible with oxidizing agents.

Literaturverweise

J.K. Stille.; D.E. James. The palladium(II)catalyzed olefin carbonylation reactions. The stereochemistry of the hydroxypalladation of cyclooctadiene . Journal of Organometallic Chemistry. 1976, 108 (3), 401-408.

Horst Kunkely, Arnd Vogler. Electronic spectrum and photoreactivity of dichloro(1,5-cyclooctadiene)-palladium(II). Journal of Organometallic Chemistry. 1998, 559 (1-2), 223-225.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Harmonized Tariff Code
2843.90
TSCA
Yes

Empfohlen

  • A13663

    Ethyl piperidine-1-acetate, 98%
  • J67828

    Tris-glycine large precast gel, 2D, 10%, 20x20cm, 22.3x20cm (back), low fluor., 1 well, for Bio-Rad® systems
  • 36703

    Starch, soluble, ACS (for iodometry)
  • 88267

    Barium titanium oxide, 99.7% (metals basis)
  • H55394

    4'-(Bromomethyl)biphenyl-2-carbonitrile, 98%

Kürzlich angesehen

Chemikalien

Life science

Metalle und Stoffe

Katalysatoren

Forschungs- und Laborbedarf