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12107-56-1 - Dichloro(1,5-cyclooctadiene)palladium(II), Pd 36.7% - 10493 - Alfa Aesar

10493 Dichloro(1,5-cyclooctadiene)palladium(II), Pd 36.7%

CAS-Nummer
12107-56-1
Synonyme

Größe Preis ($) Menge Verfügbarkeit
1g 109,00
5g 494,00
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Dichloro(1,5-cyclooctadiene)palladium(II), Pd 36.7%

MDL
MFCD00012412
EINECS
235-161-8

Chemische Eigenschaften

Formel
C8H12Cl2Pd
Molmasse
285.49
Form
Crystalline
Sensitivität
Hygroscopic
Löslichkeit
Soluble in dichloromethane

Anwendungen

Dichloro(1,5-cyclooctadiene)palladium(II) is used as catalyst for C-C bond and C-N formation, used in Heck coupling of alkynes with alkenes, Suzuki cross-coupling of aryl bromides , allylic substitution of oximes with allylic acetate and methoxycarbonylation of iodobenzene.

Bemerkungen

Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. It is sensitive to air. It is hygroscopic in nature. Incompatible with oxidizing agents.

Literaturverweise

J.K. Stille.; D.E. James. The palladium(II)catalyzed olefin carbonylation reactions. The stereochemistry of the hydroxypalladation of cyclooctadiene . Journal of Organometallic Chemistry. 1976, 108 (3), 401-408.

Horst Kunkely, Arnd Vogler. Electronic spectrum and photoreactivity of dichloro(1,5-cyclooctadiene)-palladium(II). Journal of Organometallic Chemistry. 1998, 559 (1-2), 223-225.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P260u-P201-P280a-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310a-P405-P501a

Obtain special instructions before use. Wear protective gloves and eye/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Harmonized Tariff Code
2843.90
TSCA
Yes

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