Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

15020-99-2 - Dichloro(ethylenediamine)palladium(II), Pd 44.8% - 10496 - Alfa Aesar

10496 Dichloro(ethylenediamine)palladium(II), Pd 44.8%

CAS-Nummer
15020-99-2
Synonyme

Größe Preis ($) Menge Verfügbarkeit
1g 114,33
5g 508,82
Zum Warenkorb hinzufügen Zur Angebotsanfrage hinzufügen Artikel anzeigen

Dichloro(ethylenediamine)palladium(II), Pd 44.8%

MDL
MFCD00044991

Chemische Eigenschaften

Formel
PdCl2(H2NCH2CH2NH2)
Molmasse
237.41
Form
Crystalline
Sensitivität
Hygroscopic
Löslichkeit
Very low solubility in water.

Anwendungen

Catalyst for C-C coupling reactions like Sonogashira coupling. Formation of host-guest complexes. Synthesis of mixed-metal, mixed-pyrimidine self-assembling metallacalix[n]arenes; ring-in-ring complex; binding of metal with glycose phosphates.

Bemerkungen

Stable. Hygroscopic. Not compatible with strong oxidizing agents.

Literaturverweise

Bakherad, M.; Bahramian, B.; Nasr-Isfahani, H.; Ali Keivanloo, A.; Doostmohammadi, N. Polystyrene-supported Palladium(II) Ethylenediamine Complex: A highly Active and Recyclable Catalyst for the Synthesis of 2-Benzylimidazo[2,1-b]pyridines through Heteroannulation of acetylenic Compounds. J. Heterocycl. Chem. 2009, 46 (1), 100-104.

Bardají, E. G.; Freisinger, E.; Costisella, B.; Schalley, C. A.; Brüning, W.; Sabat, M.; Lippert, B. Mixed-Metal (Platinum, Palladium), Mixed-Pyrimidine (Uracil, Cytosine) Self-Assembling Metallacalix[n]arenes: Dynamic Combinatorial Chemistry with Nucleobases and Metal Species. Chem. Eur. J. 2007, 13 (21), 6019-6039.

Bach, S. B. H.; Green, C. E.; Nagore, L. I.; Sepeda, T. G.; Merrill, G. N. Complexes of dichloro(ethylenediamine)palladium(II) observed from aqueous solutions by electrospray mass spectrometry. J. Am. Soc. Mass Spectrom. 2007, 18 (4), 769-777.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Harmonized Tariff Code
2843.90
TSCA
No

Empfohlen

  • A17880

    Thiodiglycolic acid, 98%
  • 11414

    Silver nitrate, ACS, 99.9+% (metals basis)
  • 12839

    Lithium sulfide, 99.9% (metals basis)
  • 13149

    Nitrosonium hexafluorophosphate, 96%
  • 22414

    4,5-Dihydroxynaphthalene-2,7-disulfonic acid disodium salt dihydrate, ACS

Kürzlich angesehen

Chemikalien

Life science

Metalle und Stoffe

Katalysatoren

Forschungs- und Laborbedarf