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10026-13-8 - Phosphorus(V) chloride, 98% - 10523 - Alfa Aesar

10523 Phosphorus(V) chloride, 98%

CAS-Nummer
10026-13-8
Synonyme

Größe Preis ($) Menge Verfügbarkeit
100g 34,70
500g 41,60
*4x500g 125,00
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Phosphorus(V) chloride, 98%

MDL
MFCD00011439
EINECS
233-060-3

Chemische Eigenschaften

Formel
PCl5
Molmasse
208.24
Form
Solid
Schmelzpunkt
162° subl.
Dichte
2.114
Sensitivität
Moisture Sensitive
Löslichkeit
Soluble in carbon disulfide and carbon tetrachloride.

Anwendungen

Phosphorus(V) chloride can be used for both oxidative and substitutive chlorinations, & for both organic and inorganic compounds. Dehydrating agent. Precursor to Vilsmeier reagent, lithium hexafluorophosphate electrolyite for lithium batteries.

Bemerkungen

Phosphorus(V) chloride is moisture-sensitive, & reacts violently with water. Non-flammable.

Literaturverweise

Suter, R. W.; Knachel, H. C.; Petro, V. P.; Howatson, J. H.; S. G. Shore, S. G. Nature of Phosphorus(V) Chloride in Ionizing and Nonionizing Solvents. J. Am. Chem. Soc. 1978, 95 (5), 1474-1479.

Mitrasov, Y. N.; Sosnov, D. A.; Kondrat’eva, O. V. Reaction of Spiro[2.2]pentane with Phosphorus pentachloride. Russ. J. Gen. Chem. 2013, 83 (6), 1167.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H302-H330-H314-H373

Harmful if swallowed. Fatal if inhaled. Causes severe skin burns and eye damage. May cause damage to organs through prolonged or repeated exposure.

Sicherheitshinweise: P260u-P284-P280-P303+P361+P353-P304+P340-P305+P351+P338-P320-P301+P330+P331-P405-P501a

Wear respiratory protection. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment is urgent (see label). IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Merck
14,7351
Gefahrenklasse
8
Verpackungsgruppe
II
Harmonized Tariff Code
2812.14
TSCA
Yes
RTECS
TB6125000

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