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Widely used as a catalyst for palladium-catalyzed coupling reactions including Suzuki coupling, Sonogashira coupling, Heck reaction, Negishi coupling and Stille coupling. Used in isomerization, carbonylation, oxidation, and C-C bond formation reactions.
Agrios, K. A.; Srebnik, M. Reduction of Benzylic Halides with Diethylzinc Using Tetrakis(triphenylphosphine)palladium as Catalyst. J. Org. Chem. 1993, 58 (24), 6908-6910.
Lin, D. W.; Masuda, T.; Biskup, M. B.; Nelson, J. D.; Baran, P. S. Synthesis-Guided Structure Revision of the Sarcodonin, Sarcoviolin and Hydnellin Natural Product Family. J Org Chem. 2011, 76 (4), 1013-1030.