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7787-64-6 - Bismuth(III) iodide, Puratronic®, 99.999% (metals basis) - 10656 - Alfa Aesar

10656 Bismuth(III) iodide, Puratronic®, 99.999% (metals basis)

CAS-Nummer
7787-64-6
Synonyme

Größe Preis ($) Menge Verfügbarkeit
2g 32,96
10g 116,39
50g 420,24
Zum Warenkorb hinzufügen Zur Angebotsanfrage hinzufügen Artikel anzeigen

Bismuth(III) iodide, Puratronic®, 99.999% (metals basis)

MDL
MFCD00010894
EINECS
232-127-4

Chemische Eigenschaften

Formel
BiI3
Molmasse
589.69
Form
Lump/Powder
Schmelzpunkt
408°
Siedepunkt
ca 500°
Dichte
5.778
Sensitivität
Light Sensitive & Hygroscopic
Löslichkeit
Insoluble in water. Highly soluble in ethanol, benzene, toluene and xylene, hydrochloric acid and in hydriodic acid.

Anwendungen

Polycrystalline films of bismuth triiodide are used as beta direct and digital detectors for medical imaging applications. Bismuth(III) iodide is used as an ice nucleant. It is also used in electron microscopy to reveal synapses. Addition of bismuth triiodide has been shown to improve the glass forming ability and thermal stability of Ge-Te-BiI(3) chalcogenide glasses. Solution-processable BiI<sub>3</sub> nanosheets have been shown to exhibit the potential to be used as HTLs (Hole Transport Layer) in conventional OPV (organic photovoltaic) devices.

Bemerkungen

It is stable in air. It is not hygroscopic, but decomposed by water.

Literaturverweise

Boopathi, K. M.; Raman, S.; Mohanraman, R.; Chou, F. -C.; Chen, Y. -Y.; Lee, C. H.; Chang, F. C.; Chu, C. W. Solution-processable bismuth iodide nanosheets as hole transport layers for organic solar cells. Sol. Energy Mater. Sol. Cells 2014, 121, 35-41.

Jia, R. R.; Wu, C. P.; Wu, S.; Yang, Y. X.; Chen, Y. R.; Jia, Y. Q. Synthesis and characterization of aspartic acid complexes of antimony and bismuth triiodide. Amino Acids 2006, 31 (1), 85-90.

Li, H.; Wang, M.; Huang, S.; Liu, J.; Lin, X.; Chen, Z. Preparation and Characterization of Two Bismuth(III) Iodide Inorganic/Organic Hybrid Solids. Synth. React. Inorg. M. 2011, 41 (10), 1351-1357.

Sun, J.; Nie, Q.; Wang, X.; Dai, S.; Xu, T.; Wang, G. Glass formation and properties of Ge-Te-BiI3 far infrared transmitting chalcohalide glasses. Spectrochim. Acta Part A 2011, 79 (5), 904-908.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Sicherheitshinweise: P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P363-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Merck
14,1269
Gefahrenklasse
8
Verpackungsgruppe
III
Harmonized Tariff Code
2827.60
TSCA
Yes

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