Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

10361-44-1 - Bismuth(III) nitrate hydrate, Puratronic®, 99.999% (metals basis) - 10657 - Alfa Aesar

10657 Bismuth(III) nitrate hydrate, Puratronic®, 99.999% (metals basis)

CAS-Nummer
10361-44-1
Synonyme

Größe Preis ($) Menge Verfügbarkeit
25g 78,69
100g 233,81
Zum Warenkorb hinzufügen Zur Angebotsanfrage hinzufügen Artikel anzeigen

Bismuth(III) nitrate hydrate, Puratronic®, 99.999% (metals basis)

MDL
MFCD00003460
EINECS
233-791-8

Chemische Eigenschaften

Formel
Bi(NO3)3•xH2O
Molmasse
394.99(anhy)
Form
Crystalline
Schmelzpunkt
30° dec.
Sensitivität
Hygroscopic
Löslichkeit
Slightly soluble in water; soluble in acetone, acetic acid, and glycerol. Insoluble in ethyl acetate and ethanol.

Anwendungen

It is used in electronic ceramics and fluorescent paints. It is employed as an oxidant for selective oxidation of sulfides to sulfoxides, as a nitrating reagent for synthesizing nitro aromatic compounds, and as a precursor for Dragendorff reagent for use in TLC stain and for testing the presence of alkaloids. On silica gel support, it has been reported to be an efficient catalyst for the Biginelli reaction.

Bemerkungen

Hygroscopic. Stable. On heating it decomposes to form nitrogen dioxide. Incompatible with strong acids, strong reducing agents, organic materials, and finely powdered metals.

Literaturverweise

Polanki, I. K.; Kurma, S. H.; Bhattacharya, A. K. Direct Glycosylation of Unprotected and Unactivated Sugars Using Bismuth Nitrate Pentahydrate. J. Carbohydr. Chem. 2015, 34 (4), 196-205.

Miersch, L.; Schlesinger, M.; Troff, R. W.; Schalley, C. A.; Rüffer, T.; Heinrich Lang, H.; Zahn, D.; Mehring, M. Hydrolysis of a Basic Bismuth Nitrate-Formation and Stability of Novel Bismuth Oxido Clusters. Chem-Eur. J. 2011, 17 (25), 6985-6990.

Park, Y.; McDonald, K. J.; Choi, K. Progress in Bismuth Vanadate Photoanodes for Use in Solar Water Oxidation. Chem. Soc. Rev. 2013, 42, 2321-2337.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H272-H315-H319-H335

May intensify fire; oxidizer. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P221-P210-P220-P261-P280-P305+P351+P338-P304+P340-P362-P405-P501a

Take any precaution to avoid mixing with combustibles. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep/Store away from clothing/combustible materials. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Merck
14,1271
Gefahrenklasse
5.1
Verpackungsgruppe
II
Harmonized Tariff Code
2834.29
TSCA
Yes

Empfohlen

  • A12728

    Silicone oil, for oil baths, usable range from -40 to +200°C
  • A13810

    2,2-Dimethoxypropane, 98%
  • 12523

    Copper(II) nitrate hemi(pentahydrate), ACS, 98.0-102.0%
  • 16651

    Hydrazine monohydrate, 99+%
  • 87813

    Tellurium(IV) oxide, 99.99% (metals basis)

Kürzlich angesehen

Chemikalien

Life science

Metalle und Stoffe

Katalysatoren

Forschungs- und Laborbedarf