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13778-31-9 - Copper(II) nitrate hydrate, Puratronic®, 99.999% (metals basis) - 10699 - Alfa Aesar

10699 Copper(II) nitrate hydrate, Puratronic®, 99.999% (metals basis)

CAS-Nummer
13778-31-9
Synonyme

Größe Preis ($) Menge Verfügbarkeit
5g 20,62
25g 60,81
100g 186,43
500g 493,20
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Copper(II) nitrate hydrate, Puratronic®, 99.999% (metals basis)

MDL
MFCD00149669
EINECS
221-838-5

Chemische Eigenschaften

Formel
CuN2O6•xH2O
Molmasse
187.55(anhy)
Form
Crystalline Aggregates
Sensitivität
Hygroscopic
Löslichkeit
Soluble in ethanol and water. Insoluble in ethyl acetate.

Anwendungen

It serves as a catalyst for oxidative coupling of 2,6-dimethylphenol, resulting in an important engineering polymer material. Also used in textiles and polishing agents for other metals. It is a precursor for copper oxide, which finds use as a catalyst for many organic transformations. Menke conditions employ copper nitrate for aromatic nitrations. Claycop reagent, the hydrated copper nitrate deposited on clay, finds use in many organic reactions, for example, oxidation of dithioacetals to carbonyls and thiols to disulfides.

Bemerkungen

Hygroscopic. On heating, it forms basic copper nitrate containing hydroxy anions, and on further heating, it forms cupric oxide liberating nitrogen dioxide and oxygen.

Literaturverweise

Gascon, J.; Aguado, S.; Kapteijn, F. Manufacture of Dense Coatings of Cu3(BTC)2 (HKUST-1) on alpha-Alumina. Micropor. Mesopor. Mat. 2008, 113 (1-3), 132-138.

El-Shall, M. S.; Abdelsayed, V.; Khder, A. E. R. S.; Hassan, H. M. A.; El-Kaderi, H. M.; Reich, T. E. Metallic and Bimetallic Nanocatalysts Incorporated into Highly Porous Coordination Polymer MIL-101. J. Mater. Chem. 2009, 19, 7625-7631.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H272-H314-H318-H302

May intensify fire; oxidizer. Causes severe skin burns and eye damage. Causes serious eye damage. Harmful if swallowed.

Sicherheitshinweise: P221-P210-P260-P220-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

Take any precaution to avoid mixing with combustibles. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Keep/Store away from clothing/combustible materials. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Merck
14,2643
Gefahrenklasse
5.1
Verpackungsgruppe
III
Harmonized Tariff Code
2834.29
TSCA
Yes
RTECS
GL7875000

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