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Rhodium(III) chloride hydrate is used as a catalyst to prepare acetic acid. It is also used as a catalyst for reduction, oxidation of alkenes, hydration of acetylene and isomerization of alkenes. It is involved in the hydrosilylation of alfa,beta-unsaturated esters to form dimethylketene trimethylsilyl acetals.
Hakeem, A. A.; Rajendran, J.; Kapteijn, F.; Makkee, M. Effect of rhodium on the water-gas shift performance of Fe2O3/ZrO2 and CeO2/ZrO2: Influence of rhodium precursor. Catal. Today 2015, 242, 168-177.
Hernández, J. G.; Bolm, C. [Cp* RhCl2]2: mechanosynthesis and applications in C-H bond functionalisations under ball-milling conditions. Chem. Commun. 2015, 51 (63), 12582-12584.
Gefahrenhinweise (EU): H290-H302-H318-H341
May be corrosive to metals. Harmful if swallowed. Causes serious eye damage. Suspected of causing genetic defects.
Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Wear eye/face protection. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.