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26023-84-7 - Dihydrogen hexachloroplatinate(IV) hydrate, 99.9% (metals basis) - CPA - Chloroplatinic acid - 11051 - Alfa Aesar

11051 Dihydrogen hexachloroplatinate(IV) hydrate, 99.9% (metals basis)

CAS-Nummer
26023-84-7
Synonyme
CPA
Chloroplatinic acid

Größe Preis ($) Menge Verfügbarkeit
1g 90,30
5g 390,00
25g 1774,00
100g Pricing available on request. Click Add to Quote Request button and specify size.
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Dihydrogen hexachloroplatinate(IV) hydrate, 99.9% (metals basis)

MDL
MFCD00149909
EINECS
607-848-6

Chemische Eigenschaften

Formel
H2PtCl6•xH2O
Molmasse
409.82(anhy)
Form
Crystalline
Schmelzpunkt
60° dec.
Dichte
2.430
Sensitivität
Hygroscopic
Löslichkeit
Soluble in water, ethanol, ether, ethyl acetate and acetone. Insoluble in nitric acid.

Anwendungen

Catalysis, electroplating, photography, platinum mirrors, printing for etching of zinc, producing fine color in glass and porcelain, indelible ink, microscopy.Dihydrogen hexachloroplatinate(IV) hexahydrate is used for the determination of potassium. It is also used for the purification of platinum by treating it with ammonium chloride followed by heating of ammonium hexachloroplatinate with hydrogen yields elemental platinum. It also finds application in catalysis, electroplating, photography, platinum mirrors, printing for etching of zinc, producing fine color in glass and porcelain, indelible ink and microscopy. It is a precursor for the preparation of other platinum catalysts. In addition to this, it is also used as an analytical reagent.

Bemerkungen

Light sensitive. Hygroscopic. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents and bases.

Literaturverweise

Kondo, M.; Ishigure, S.; Maki, Y.; Dewa, T.; Nango, M.; Amao, Y. Photoinduced hydrogen production with photosensitization of Zn chlorophyll analog dimer as a photosynthetic special pair model. Int. J. Hydrogen Energy 2015, 40 (15), 5313-5318.

Wang, J.; Zhao, J.; Osterloh, F. E. Photochemical charge transfer observed in nanoscale hydrogen evolving photocatalysts using surface photovoltage spectroscopy. Energy Environ. Sci. 2015, 8 (10), 2970-2976.

Wang, P.; Yue, Z.; Zhang, J.; Feng, S. Reactions and Mechanisms of Chloroplatinic Acid Hexahydrate with Dimethyldi(4-N,N-dimethylaminophenyl)silane. Inorg. Chem. Commun. 2011, 14 (6), 1027-1031.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H301-H317-H334-H314-H318-H290-H400-H410

Toxic if swallowed. May cause an allergic skin reaction. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage. May be corrosive to metals. Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects.

Sicherheitshinweise: P260-P285-P261-P273-P301+P310-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. In case of inadequate ventilation wear respiratory protection. Avoid breathing dust/fume/gas/mist/vapours/spray. Avoid release to the environment. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Merck
14,7526
Gefahrenklasse
8
Verpackungsgruppe
III
Harmonized Tariff Code
2843.90
TSCA
Yes
RTECS
TP1500000

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