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19423-87-1 - Ytterbium(III) chloride hydrate, REacton®, 99.9% (REO) - 11193 - Alfa Aesar

11193 Ytterbium(III) chloride hydrate, REacton®, 99.9% (REO)

CAS-Nummer
19423-87-1
Synonyme

Größe Preis ($) Menge Verfügbarkeit
10g 35,54
50g 128,75
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Ytterbium(III) chloride hydrate, REacton®, 99.9% (REO)

MDL
MFCD00149885
EINECS
233-800-5

Chemische Eigenschaften

Formel
YbCl3•xH2O (x≈6)
Molmasse
279.40(anhy)
Form
Wet Crystalline Aggregates
Schmelzpunkt
150-155°
Dichte
2.58
Sensitivität
Hygroscopic
Löslichkeit
Soluble in water.

Anwendungen

Ytterbium(III) chloride hydrate is used as an effective catalyst to prepare acetals by reacting with trimethyl orthoformate. It reacts with N-alkylsalicylideneimines to prepare yttrium(III) Schiff base complexes. It is widely used as NMR shift reagent, calcium ion probe and in DNA microarrays. Its anhydrous form acts as a Lewis acid and catalyzes the alkylation reactions such as aldol reaction and Pictet-Spengler reaction.

Bemerkungen

Hygroscopic. Incompatible with water, oxidizing agents.

Literaturverweise

Knopf, K. M.; Crundwell, G.; Westcott, B. L. Crystal structure of hexaaquadichloridoytterbium(III) chloride. Acta Cryst. 2015, E71 (6), i5.

Ogata, T.; Narita, H.; Tanaka, M. Adsorption behavior of rare earth elements on silica gel modified with diglycol amic acid. Hydrometallurgy 2015, 152, 178-182.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Merck
14,10105
Harmonized Tariff Code
2846.90
TSCA
Yes

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