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Used as an electrolyte in Li-ion batteries.Lithium hexafluorophosphate is used as an electrolyte in lithium batteries, ceramic industries and for welding electrode manufacturing. It is also used in commercial secondary batteries, prism spectrometer and x-ray monochromator. Further, it catalyzes the tetrahydropyranylation of tertiary alcohol.
Wang, D. Y.; Xiao, A.; Wells, L.; Dahn, J. R. Effect of Mixtures of Lithium Hexafluorophosphate (LiPF6) and Lithium Bis (fluorosulfonyl) imide (LiFSI) as Salts in Li [Ni1/3Mn1/3Co1/3]O2/Graphite Pouch Cells. J. Electrochem. Soc. 2015, 162 (1), A169-A175.
Kraft, V.; Grützke, M.; Weber, W.; Menzel, J.; Wiemers-Meyer, S.; Winter, M.; Nowak, S. Two-dimensional ion chromatography for the separation of ionic organophosphates generated in thermally decomposed lithium hexafluorophosphate-based lithium ion battery electrolytes. J. Chromatogr. A 2015, 1409, 201-209.
Gefahrenhinweise (EU): H302-H311-H314-H318
Harmful if swallowed. Toxic in contact with skin. Causes severe skin burns and eye damage. Causes serious eye damage.
Do not breathe dusts or mists. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.