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Silver(I) fluoride is used as a fluorination and desilylation reagent in organic synthesis. In medical filed, it is used as topical caries in aqueous form in dentistry. It is employed in organofluorine chemistry for addition of fluoride across multiple bonds, especially to prepare perfluoroalkylsilver(I) by reacting with alkenes. Further, it is involved in the preparation of tetralkylammonium fluorides by the reaction with tetralkylammonium bromide. In addition to this, it is used as a desulfuration-fluorination reagent on thiourea derived substrates.
Braganza, J. F.; Bernier, L.; Botrous, I.; Collins, M. R.; Li, B.; McAlpine, I.; Ninkovic, S.; Ren, S.; Sach, N.; Tran-Dube, M.; Zeng, Q.; Zheng, B. Improved cyclization conditions to prepare 6-substituted pyrazolo[1,5-a]pyridines and pyrazolo[1,5-a]pyrazines using catalytic Ag(I) and Au(III) salts. Tetrahedron Lett. 2015, 56 (42), 5757-5760.
Kremlev, M. M.; Mushta, A. I.; Tyrra, W.; Yagupolskii, Y. L.; Naumann, D.; Schäfer, M. Approaches to prepare perfluoroalkyl and pentafluorophenyl copper couples for cross-coupling reactions with organohalogen compounds. Dalton Trans. 2015, 44 (45), 19693-19699.
Gefahrenhinweise (EU): H302-H312-H332-H314-H318
Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage.
Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.