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13453-78-6 - Lithium perchlorate trihydrate, Reagent Grade - 11638 - Alfa Aesar

11638 Lithium perchlorate trihydrate, Reagent Grade

CAS-Nummer
13453-78-6
Synonyme

Größe Preis ($) Menge Verfügbarkeit
250g 52,70
1kg 148,00
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Lithium perchlorate trihydrate, Reagent Grade

MDL
MFCD00149765
EINECS
232-237-2

Chemische Eigenschaften

Formel
ClLiO4•3H2O
Molmasse
160.45 (106.40anhy)
Form
Crystalline
Dichte
1.84
Löslichkeit
Highly soluble in water, methanol, ethanol, ethyl acetate, diethyl ether, and acetone.

Anwendungen

It is used as an oxygen source for chemical oxygen generators, as it liberates oxygen at high temperatures. Excellent solubility of lithium perchlorate permits its use in Diels-Alder reactions. It is also employed in lithium-ion batteries as an electrolyte, and act as chaotropic agent to denature proteins. It is used in Baylis-Hillman reaction as a catalyst in the coupling of alpha,beta-unsaturated carbonyl compounds with aldehydes.

Bemerkungen

Hygroscopic. Strong oxidizer and a corrosive solid. Above 400°C, it decomposes to give lithium chloride and oxygen.

Literaturverweise

Qiu, X.; Lu, L.; Leng, J.; Yu, Y.; Wang, W.; Jiang, M.; Bai, L. An enhanced electrochemical platform based on graphene oxide and multi-walled carbon nanotubes nanocomposite for sensitive determination of Sunset Yellow and Tartrazine. Food Chemistry 2016, 190, 889-895.

Toth, P. S.; Dryfe, R. A. W. Novel organic solvents for electrochemistry at the liquid/liquid interface. Analyst 2015, 140, 1947-1954.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H272-H315-H319-H335

May intensify fire; oxidizer. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P221-P210v-P220-P305+P351+P338-P405-P501a

Take any precaution to avoid mixing with combustibles. Keep/Store away from clothing/combustible materials. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Merck
14,5539
Gefahrenklasse
5.1
Verpackungsgruppe
II
Harmonized Tariff Code
2829.90
TSCA
Yes
RTECS
SC8750000

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