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7681-82-5 - Sodium iodide, 99.9% (metals basis) - 11665 - Alfa Aesar

11665 Sodium iodide, 99.9% (metals basis)

CAS-Nummer
7681-82-5
Synonyme

Größe Preis ($) Menge Verfügbarkeit
100g 48,78
500g 190,80
2kg 612,00
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Sodium iodide, 99.9% (metals basis)

MDL
MFCD00003532
EINECS
231-679-3

Chemische Eigenschaften

Formel
NaI
Molmasse
149.89
Form
Powder
Schmelzpunkt
651°
Siedepunkt
1300-1304°
Dichte
3.67
Brechungsindex
1.7745
Sensitivität
Hygroscopic
Löslichkeit
Very soluble in water and liquid ammonia. Freely soluble in acetone, formic acid, formamide, methanol, and acetonitrile. Soluble in N,N-dimethylformamide.

Anwendungen

Sodium iodide is widely used for halide exchange (Finkelstein reaction), for example in the conversion of an alkyl chloride, allyl chloride and arylmethyl chloride into their respective iodides, which are precursors for pharmaceutical and fine chemical products. They are used to ehnance the efficiency of the formation of Wittig adducts from less reactive chlorides and bromides. Appropriate prepartions find use as a nutrient supplement. Sodium iodide is used as the precursor to the control agent in ab initio emulsion polymerization. Sodium iodide finds use in the determination of dissolved oxygen in the modified Winkler method, synthesis of the fluorescent dye coppersensor-1 (CS1) for imaging labile copper pools in biological samples, and the cleavage of esters, lactones, carbamates and ethers in combination with chlorotrimethylsilane.

Bemerkungen

Deliquescent. Store in a tightly closed container. Incompatible with strong oxidizing agents and acids.

Literaturverweise

Penheiter, A. R.; Russell, S. J.; Carlson, S. K. The Sodium Iodide Symporter (NIS) as an Imaging Reporter for Gene, Viral, and Cell-based Therapies. Curr. Gene Ther. 2012, 12, (1), 33-47.

Tonnar, J.; Lacroix-Desmazes, P. Use of Sodium Iodide as the Precursor to the Control Agent in Ab Initio Emulsion Polymerization. Angew. Chem. Int. Ed. 2008, 47, 1294-1297.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319-H335-H303

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. May be harmful if swallowed.

Sicherheitshinweise: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Merck
14,8631
Harmonized Tariff Code
2827.60
TSCA
Yes
RTECS
WB6475000

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