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26042-63-7 - Silver hexafluorophosphate, 98% - 11873 - Alfa Aesar

11873 Silver hexafluorophosphate, 98%

CAS-Nummer
26042-63-7
Synonyme

Größe Preis ($) Menge Verfügbarkeit
1g 35,60
5g 107,00
25g 388,00
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Silver hexafluorophosphate, 98%

MDL
MFCD00003415
EINECS
247-428-6

Chemische Eigenschaften

Formel
AgF6P
Molmasse
252.83
Form
Powder
Schmelzpunkt
102° dec.
Sensitivität
Light Sensitive
Löslichkeit
Soluble in organic solvents such as benzene, toluene, and acetonitrile.

Anwendungen

It is commonly used as an oxidant forming silver metal. It is often used as a reagent in inorganic and organometallic chemistry. It is used in the preparation of engineering novel materials as well as in preparation of supra molecular Ag(I) complexes. It is used in the development of new catalysts, replacing halide ligands with the weakly coordinating hexafluorophosphate anion.

Bemerkungen

Stable under room temperatures and pressures. Moisture sensitive, hygroscopic, and may discolor on exposure to light. Incompatible with strong oxidizing agents and strong acids.

Literaturverweise

Galan, R. F.; Manzano, B. R.; Otero, A.; Lanfranchi, M.; Pellinghelli, M. A. 19F and 31P NMR evidence for silver hexafluorophosphate hydrolysis in solution. New palladium difluorophosphate complexes and x-ray structure determination of [Pd(.eta.3-2-Me-C3H4)(PO2F2)(PCy3)]Inorg. Chem. 1994, 33 (10), 2309-2312.

Hirsch, K. A.; Wilson, S. R.; Moore, J. S. Coordination Networks of 3,3‘-Dicyanodiphenylacetylene and Silver(I) Salts:? Structural Diversity through Changes in Ligand Conformation and Counter ion. Inorg. Chem. 1997, 36 (14), 2960-2968.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Sicherheitshinweise: P273-P280-P303+P361+P353-P305+P351+P338-P310a

Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Weitere Referenzen

Gefahrenklasse
8
Verpackungsgruppe
II
Harmonized Tariff Code
2843.29
TSCA
Yes

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