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10026-11-6 - Zirconium(IV) chloride, Reactor Grade, 99.5+% (metals basis) - Zirconium tetrachloride - 12104 - Alfa Aesar

12104 Zirconium(IV) chloride, Reactor Grade, 99.5+% (metals basis)

CAS-Nummer
10026-11-6
Synonyme
Zirconium tetrachloride

Größe Preis ($) Menge Verfügbarkeit
10g 25,15
100g 35,68
500g 119,42
2kg 336,81
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Zirconium(IV) chloride, Reactor Grade, 99.5+% (metals basis)

MDL
MFCD00011306
EINECS
233-058-2

Chemische Eigenschaften

Formel
ZrCl4
Molmasse
233.03
Form
Powder
Schmelzpunkt
331° subl.
Dichte
2.803
Sensitivität
Moisture Sensitive
Löslichkeit
Soluble in alcohol, ether, hydrochloric acid.

Anwendungen

Zirconium tetrachloride is commonly utilized as a Lewis acid catalyst in many organic synthesis reactions. It is an important source for organometallic complexes of zirconium. It is practiced in many areas like nuclear industry, metal industry, photography, glass, and ceramic industry.

Bemerkungen

It is stable under room temperatures. Strongly hygroscopic and decomposes in water forming ZrOCl<sub>2</sub> and HCl.

Literaturverweise

Meshram, H. M.; Premalatha, K.; Rameshbabu, K.; Eeshwaraiah, B.; Yadav, J. S. Zirconium(IV) Chloride Catalyzed Cyclization of ortho-Allylphenols: Synthesis of 2-Methyl-2,3-dihydrobenzofurans. Synth. Commun. 2004, 34 (17), 3091-3097.

Smitha, G.; Chandrasekhar, S.; Sanjeeva Reddy, C. Applications of Zirconium(IV) Chloride in Organic Synthesis. Synthesis 2008, 6, 829-855.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H314-H318-H302

Causes severe skin burns and eye damage. Causes serious eye damage. Harmful if swallowed.

Sicherheitshinweise: P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P301+P312-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Merck
14,10174
Gefahrenklasse
8
Verpackungsgruppe
III
Harmonized Tariff Code
2827.39
TSCA
Yes
RTECS
ZH7175000

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