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34513-98-9 - Ruthenium(III) nitrosylnitrate, Ru 31.3% min - 12175 - Alfa Aesar

12175 Ruthenium(III) nitrosylnitrate, Ru 31.3% min

CAS-Nummer
34513-98-9
Synonyme

Größe Preis ($) Menge Verfügbarkeit
1g 74,04
5g 261,30
25g 1180,38
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Ruthenium(III) nitrosylnitrate, Ru 31.3% min

MDL
MFCD00016313
EINECS
252-068-8

Chemische Eigenschaften

Formel
N4O10Ru
Molmasse
317.09
Form
Crystalline
Schmelzpunkt
dec.
Löslichkeit
Miscible with cold water.

Anwendungen

Ruthenium(III) nitrosyl nitrate used as a catalyst in various reactions namely hydrogenation, carbonylation, hydrosilylation, hydrofomylation, C-X coupling (eg Heck, Suzuki, Stille) and chiral catalysis reactions. It is also used in the production of thick-film resistors.

Bemerkungen

Incompatible with reducing agents, phosphorus, sulfur and organic matter.

Literaturverweise

Zoehrer, H.; Mayr, F.; Vogel, F. Stability and Performance of Ruthenium Catalysts Based on Refractory Oxide Supports in Supercritical Water Conditions. Energy Fuels 2013, 27 (8), 4739-4747.

Rose, M. J.; Mascharak, P. K. Photoactive Ruthenium Nitrosyls: Effects of Light and Potential Application as NO Donors. Coord. Chem. Rev. 2008, 252 (18-20), 2093-2114.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H272-H314-H318-H290

May intensify fire; oxidizer. Causes severe skin burns and eye damage. Causes serious eye damage. May be corrosive to metals.

Sicherheitshinweise: P221-P210-P260-P220-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

Take any precaution to avoid mixing with combustibles. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Keep/Store away from clothing/combustible materials. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Gefahrenklasse
5.1
Verpackungsgruppe
II
Harmonized Tariff Code
2843.90
TSCA
Yes

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