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7782-61-8 - Iron(III) nitrate nonahydrate, 98+% (metals basis) - 12226 - Alfa Aesar

12226 Iron(III) nitrate nonahydrate, 98+% (metals basis)

CAS-Nummer
7782-61-8
Synonyme

Größe Preis ($) Menge Verfügbarkeit
100g 21,30
1kg 44,10
5kg 83,50
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Iron(III) nitrate nonahydrate, 98+% (metals basis)

MDL
MFCD00149708
EINECS
233-899-5

Chemische Eigenschaften

Formel
FeN3O9•9H2O
Molmasse
403.99 (241.86anhy)
Form
Crystalline, Contains excess HNO3
Schmelzpunkt
47°
Siedepunkt
125° dec.
Dichte
1.684
Sensitivität
Moisture Sensitive
Löslichkeit
Soluble in water, alcohol and acetone.

Anwendungen

It is used as catalyst for the synthesis of sodium amide from sodium and ammonia, and for etching of silver and silver alloys. Ferric nitrate is used in the synthesis of organically templated iron phosphates, and acts as an efficient catalyst in enamination of beta dicarbonyl compounds to beta enaminones. Ferric nitrate impregnated clays are useful as oxidizing agents. Clayfen, produced from ferric nitrate and montmorillonite, is used for the oxidation of thiols to disulfide, and alcohols to aldehydes. Ferric nitrate is useful for regio- and stereo-selective nitration of various aromatic, aliphatic, and heteroaromatic olefins. This reaction provides nitroolefins with excellent E-selectivity. With Keggin-type heteropoly acids, it selectively oxidizes various hydroxy groups.

Bemerkungen

Keep away from materials like organic and powdered metals.

Literaturverweise

Soni, P. A.; Gupta, P. K.; Maurya, C. K.; Halve, A. K.; Ganesan, K. Synthesis of 1,2-diones from 1,2-diols using iron(III) nitrate as oxidant under microwave irradiation. Tetrahedron Lett. 2015, 56 (21), 2817-2819.

Jastrzebski, R.; Van den Berg, E. J.; Weckhuysen, B. M.; Bruijnincx, P. C. A. Sustainable production of dimethyl adipate by non-heme iron(III) catalysed oxidative cleavage of catechol. Catal. Sci. Technol. 2015, 5, 2103-2109.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H272-H315-H319

May intensify fire; oxidizer. Causes skin irritation. Causes serious eye irritation.

Sicherheitshinweise: P221-P210v-P220-P280a-P305+P351+P338-P501a

Take any precaution to avoid mixing with combustibles. Keep/Store away from clothing/combustible materials. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Merck
14,4027
Gefahrenklasse
5.1
Verpackungsgruppe
III
Harmonized Tariff Code
2834.29
TSCA
Yes
RTECS
NO7175000

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