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It is used as a catalyst for Friedel-Crafts acylation and alkylation of aromatic compounds. It is one of the most commonly employed Lewis acids for a wide variety of organic transformations. It catalyzes the ene reaction, polymerization, and isomerization reactions. For example, it can be used to synthesis ethyl benzene which is a precursor for producing polystyrene. It can be used for producing dodecylbenzene, a key intermediate for detergents. It is useful in the production of anthroquinone, the presursor for dyestuffs. It is used in the synthesis of bis(arene) metal complexes, through Fischer-Hafner synthesis. Gattermann-Koch reaction employs aluminum chloride for introducing formyl group onto aromatic rings.
Schwiderski, M.; Kruse, A. Catalytic effect of aluminium chloride on the example of the conversion of sugar model compounds. J. Mol. Catal. A Chem. 2015, 402, 64-70.
Ti, H.; Zhang, R.; Zhang, M.; Wei, Z.; Chi, J.; Deng, Y.; Zhang, Y. Effect of extrusion on phytochemical profiles in milled fractions of black rice. Food Chemistry 2015, 178, 186-194.
Gefahrenhinweise (EU): H314
Causes severe skin burns and eye damage.
Do not breathe dusts or mists. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.