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Cobalt(II) chloride is used in humidity indicator in weather instruments. In the anhydrous form, it finds use in electroplating of cobalt, in organic chemistry and is a precursor to cobaltocene, (bis(cyclopentadienyl)cobalt(II), which is a good reducing agent. It also serves as a Lewis acid. Cobalt chloride is an indicator for water in desiccants, owing to the reversible hydration/dehydration coupled with distinct color change. Cobalt chloride is useful for producing invisible ink as it turns blue when heated and becomes invisible once it gets cooled. Cobalt(II) chloride catalyzes cross coupling of aryl halides or vinyl halides with aryl grignard reagents in excellent yields.
Holstein, H.; Ranebo, Y.; Rääf, C. L. Human metabolism of orally administered radioactive cobalt chloride. J Environ. Radioactiv. 2015, 143, 152-158.
Pereira, A. C.; Reis, B. F.; Rocha, F. R. P. An air carrier flow system for the spectrophotometric determination of water in biodiesel exploiting bleaching of the cobalt chloride complex. Talanta 2015, 131, 21-25.
Cahiez, G.; Moyeux, A. Cobalt-catalyzed cross coupling reactions. Chem. Rev. 2010, 110, 1435-1462.
Gefahrenhinweise (EU): H302-H334-H317-H341-H350-H360
Harmful if swallowed. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. Suspected of causing genetic defects. May cause cancer. May damage fertility or the unborn child.
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