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34513-98-9 - Ruthenium(III) nitrosylnitrate solution, Ru 1.5% w/v - 12630 - Alfa Aesar

12630 Ruthenium(III) nitrosylnitrate solution, Ru 1.5% w/v

CAS-Nummer
34513-98-9
Synonyme

Größe Preis ($) Menge Verfügbarkeit
50ml 82,71
250ml 357,41
1000ml 1086,12
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Ruthenium(III) nitrosylnitrate solution, Ru 1.5% w/v

MDL
MFCD00016313
EINECS
252-068-8

Chemische Eigenschaften

Formel
N4O10Ru
Molmasse
317.09
Form
Liquid
Dichte
1.07
Löslichkeit
Miscible with cold water.

Anwendungen

Ruthenium(III) nitrosyl nitrate used as a catalyst in various reactions namely hydrogenation, carbonylation, hydrosilylation, hydrofomylation, C-X coupling (eg Heck, Suzuki, Stille) and chiral catalysis reactions. It is also used in the production of thick-film resistors.

Bemerkungen

1.1Incompatible with reducing agents, phosphorus, sulfur and organic matter.

Literaturverweise

Rathgeb, A.; Bohm, A.; Novak, M. S.; Gavriluta, A.; Domotor, O.; Tommasino, J. B.; Enyedy, E. A.; Shova, S.; Meier, S.; Jakupec, M. A.; Luneau, D.; Arion, V. B. Ruthenium-Nitrosyl Complexes with Glycine, l-Alanine, l-Valine, l-Proline, d-Proline, l-Serine, l-Threonine, and l-Tyrosine: Synthesis, X-ray Diffraction Structures, Spectroscopic and Electrochemical Properties, and Antiproliferative Activity. Inorg. Chem. 2014, 53 (5), 2718-2729.

Lopes, L. M.; Garcia, A. R.; Fidalgo, A.; Ilharco, L. M. Encapsulation of Ruthenium Nitrosylnitrate and DNA Purines in Nanostructured Sol-Gel Silica Matrices. Langmuir 2009, 25 (17), 10243-10250.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H272-H314

May intensify fire; oxidizer. Causes severe skin burns and eye damage.

Sicherheitshinweise: P221-P210-P260-P220-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

Take any precaution to avoid mixing with combustibles. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Keep/Store away from clothing/combustible materials. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Gefahrenklasse
8
Verpackungsgruppe
II
Harmonized Tariff Code
2843.90
TSCA
Yes

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