I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.
Chloro(1,5-cyclooctadiene)iridium(I) dimer is widely used as a precursor to other iridium complexes, which finds application in homogeneous catalysis like carbonylation, hydrosilylation, hydrofomylation, asymmetric allylic substitutions, metathesis and chiral catalysis reactions. It is involved in the preparation of Crabtree's catalyst, which is used for hydrogenation and hydrogen-transfer reactions.
John, J.; Wilson-Konderka, C.; Metallinos, C. Low Pressure Asymmetric Hydrogenation of Quinolines using an Annulated Planar Chiral N-Ferrocenyl NHC-Iridium Complex. Adv. Synth. Catal. 2015, 357 (9), 2071-2081.
El Amouri, H.; Gruselle, M.; Jaouén, G. bis[Dichloro(η-pentamethylcyclopentadienyl)rhodium(III) and-iridium(III)] from bis[Chloro(1, 5-cyclooctadiene)rhodium(I) and-iridium(I)] Oxidation, and Formation of 1, 5-Cyclooctadiene(η-pentamethylcyclopentadienyl)rhodium(I). Synth. React. Inorg. Met.-Org. Chem. 2015, 24 (3), 395-400.
Gefahrenhinweise (EU): H315-H319-H335
Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.