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32005-36-0 - Bis(dibenzylideneacetone)palladium(0) - 12764 - Alfa Aesar

12764 Bis(dibenzylideneacetone)palladium(0)

CAS-Nummer
32005-36-0
Synonyme

Größe Preis ($) Menge Verfügbarkeit
0.25g 20,00
1g 45,00
5g 152,44
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Bis(dibenzylideneacetone)palladium(0)

MDL
MFCD00051942

Chemische Eigenschaften

Formel
C34H28O2Pd
Molmasse
575.00
Form
Powder, Packaged under argon
Schmelzpunkt
135° dec.
Sensitivität
Air & Moisture Sensitive
Löslichkeit
Slightly soluble in CH{2}Cl{2}, CHCl{3} and benzene.Soluble in dichloromethane, chloroform, 1,2-dichloroethane, acetone, acetonitrile and benzene. Insoluble in water.

Anwendungen

Hydrogenation, isomerization, carbonylation, oxidation, C-C bond formation.Bis(dibenzylideneacetone)palladium(0) is used as a reagent for the preparation of allylic substituted cyclopentadienes. It acts as a homogeneous catalyst as well as in the alkylation of allyl acetates by various nucleophiles. Further, it is used in Suzuki reaction.

Bemerkungen

Incompatible with strong oxidizing agents.

Literaturverweise

Chan, K. S.; Fu, H. Y.; Yu, J. Q. Palladium(II)-Catalyzed Highly Enantioselective C-H Arylation of Cyclopropylmethylamines. J. Am. Chem. Soc. 2015, 137 (5), 2042-2046.

Son, S.; Lee, H.; Kwak, C.; Lee, J.; Ahn, H.; Chung, M. A Study of Phosphorescent Light Emitting Using Cyclometalated Pt(II) Complexes. J. Nanosci. Nanotechnol. 2015, 15 (7), 5338-5341.

Weitere Referenzen

Harmonized Tariff Code
2843.90
TSCA
No

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