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Ingold's method of competitive nitration has been used in order to determine relative reactivities of alkylbenzenes and benzene in homogeneous mononitrations with nitronium tetrafluoroborate in tetramethylene sulfone solutions. Oxidation of both exo-and endo-2-bromonorbornane with nitronium tetrafluoroborate in acetonitrile afforded N-exo-2-norbornylacetamide. Used in the synthesis and characterization of new polyhydroxyorganocarboxylated fullerene derivatives through the electrophilic addition of nitronium tetrafluoroborate onto fullerenes in the presence of arenecarboxylic acid in a nonaqueous medium.
G. Oláh,; S. Kuhn,; A. Mlinkó. Aromatic substitution. Part II. Nitration of aromatic compounds with nitronium tetrafluoroborate and other stable nitronium salts. J. Chem. Soc., . 1956, 4257-4258.
Robert D. Bach,; Joseph W. Holubka,; Thomas H. Taaffee. Reaction of optically active exo- and endo-2-bromonorbornane with nitronium tetrafluoroborate in acetonitrile. Evidence for a carbenium ion pathway . J. Org. Chem., 1979, 44 (1), 35-38.
Gefahrenhinweise (EU): H314-H318
Causes severe skin burns and eye damage. Causes serious eye damage.
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