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39588 Bis(cyclopentadienyl)vanadium dichloride, 95%

CAS-Nummer
12083-48-6
Synonyme
Vanadocene dichloride

Stock No. Größe Preis ($) Menge Verfügbarkeit
39588-03 1g 52,60
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Bis(cyclopentadienyl)vanadium dichloride, 95%

MDL
MFCD00014260
EINECS
235-150-8

Chemische Eigenschaften

Formel
C10H10Cl2V
Molmasse
252.04
Form
Crystalline, Packaged under argon
Schmelzpunkt
250° dec.
Dichte
1.60
Storage & Sensitivity
Moisture Sensitive. Air Sensitive. Store under Nitrogen. Ambient temperatures.
Löslichkeit
Reacts with water

Anwendungen

Bis(cyclopentadienyl)vanadium(IV) dichloride is a catalyst for solvent free, room temperature preparation of vicinal amino alcohols as fungistatic agents, catalyst fot oligomerization reactions via the Aufbau propagation reaction and as a catalyst for aqueous polymerization reactions using oxygen as a co catalyst. It is used as a catalyst for dl-selective pinacol-type coupling reactions, as an affecter of crystal growth of calcium carbonate and and as an inhibitor of human topoisomerase II enzyme with antitumor activity.

Bemerkungen

Air & Moisture Sensitive. Incompatible with oxidizing agents.

Literaturverweise

Dennis P. Bakalik.; Robert G. Hayes. Electron paramagnetic resonance studies of the electronic structure of bis(cyclopentadienyl)vanadium dichloride and a comparison with simple molecular orbital calculations. Inorg. Chem. 1972, 11 (8), 1734-1738.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H301-H315-H319-H335

Toxic if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P261-P280a-P301+P310a-P305+P351+P338-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF SWALLOWED: Immediately call a POISON CENTER/doctor IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Gefahrenklasse
6.1
Verpackungsgruppe
III
Harmonized Tariff Code
2931.90
TSCA
No
RTECS
YW1580000

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