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43430 Tin(II) bromide, 99.2%

CAS-Nummer
10031-24-0
Synonyme

Stock No. Größe Preis ($) Menge Verfügbarkeit
43430-06 5g 19,20
43430-14 25g 64,50
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Tin(II) bromide, 99.2%

MDL
MFCD00011239
EINECS
233-087-0

Chemische Eigenschaften

Formel
SnBr2
Molmasse
278.51
Form
Powder
Schmelzpunkt
215°
Siedepunkt
623°
Dichte
5.12
Storage & Sensitivity
Ambient temperatures.
Löslichkeit
Soluble in alcohol, ether, acetone, pyridine and dimethyl sulfoxide.

Anwendungen

Stannous bromide acts a lewis acid. It is used to prepare alkyl tin compounds and in the spectrophotometric determination of iridium. It is involved in regioselective mono-etherfications of vicinal diols with diazo compounds. It acts as a catalyst to produce resinous lactone high polymers. It serves as a potent reducing agent.

Bemerkungen

Moisture, air and light sensitive. Store in a tightly closed container. Prolonged exposure to atmosphere may degrade the product.

Literaturverweise

Braunschweig, H.; Ceik, M. A.; Dewhurst, R. D.; Heid, M.; Hupp, F.; Sen, S. S. Stepwise isolation of low-valent, low-coordinate Sn and Pb mono- and dications in the coordination sphere of platinum. Chem. Sci. 2015, 6, 425-435.

Avery, J. C.; Hanson, M. A.; Herber, R. H.; Bladek, K. J.; Rupar,P. A.; Nowik, I.; Huang, Y.; Baines, K. M. Cationic Cryptand Complexes of Tin(II). Inorg. Chem. 2012, 51 (13), 7306-7316.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Sicherheitshinweise: P260u-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

Do not breathe dusts or mists. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Merck
14,8782
Gefahrenklasse
8
Verpackungsgruppe
III
Harmonized Tariff Code
2827.59
TSCA
Yes

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