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44145 Lithium dimethylamide, 96%

CAS-Nummer
3585-33-9
Synonyme

Stock No. Größe Preis ($) Menge Verfügbarkeit
44145-06 5g 95,30
44145-14 25g 396,00
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Lithium dimethylamide, 96%

MDL
MFCD00008295
EINECS
222-714-3

Chemische Eigenschaften

Formel
C2H6LiN
Molmasse
51.02
Form
Powder/Lump
Schmelzpunkt
dec.
Storage & Sensitivity
Moisture Sensitive. Air Sensitive. Store under Nitrogen. Ambient temperatures.
Löslichkeit
Reacts violently with water.

Anwendungen

It is used in the synthesis of some d0 organoimido complexes of the early transition metals and in meta rearrangement in the reaction of triphenyl-(p-bromophenyl)-silane.

Bemerkungen

Store away from air, water/moisture and oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Store under inert gas.

Literaturverweise

Catherine Fressigné, et al.A DFT Theoretical Analysis of Aldehyde Condensation Pathways onnto Methyllithium, Lithium Dimethylamide, and Their Aggregates.J. Org. Chem.,2000,65(26), 8899-8907.

Shinsuke Fukuoka, et al. Reaction of phenylacetylene with nickel carbonyl and lithium dimethylamide.J. Org. Chem.,1968,33(7), 2973-2975.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H250-H261-H314-H318

Catches fire spontaneously if exposed to air. In contact with water releases flammable gas. Causes severe skin burns and eye damage. Causes serious eye damage.

Sicherheitshinweise: P222-P280-P305+P351+P338-P310a-P370+P378i-P402+P404

Do not allow contact with air. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor In case of fire: Use for extinction: Fire-extinguishing powder. Store in a dry place. Store in a closed container.

Weitere Referenzen

Beilstein
3618233
Gefahrenklasse
4.2
Verpackungsgruppe
I
Harmonized Tariff Code
2921.11
TSCA
No

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