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It is used in the synthesis of some d0 organoimido complexes of the early transition metals and in meta rearrangement in the reaction of triphenyl-(p-bromophenyl)-silane.
Catherine Fressigné, et al.A DFT Theoretical Analysis of Aldehyde Condensation Pathways onnto Methyllithium, Lithium Dimethylamide, and Their Aggregates.J. Org. Chem.,2000,65(26), 8899-8907.
Shinsuke Fukuoka, et al. Reaction of phenylacetylene with nickel carbonyl and lithium dimethylamide.J. Org. Chem.,1968,33(7), 2973-2975.
Gefahrenhinweise (EU): H250-H261-H314-H318
Catches fire spontaneously if exposed to air. In contact with water releases flammable gas. Causes severe skin burns and eye damage. Causes serious eye damage.
Do not allow contact with air. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor In case of fire: Use for extinction: Fire-extinguishing powder. Store in a dry place. Store in a closed container.