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44226 Lithium perchlorate, anhydrous, 99.99% (metals basis)

CAS-Nummer
7791-03-9
Synonyme

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Lithium perchlorate, anhydrous, 99.99% (metals basis)

MDL
MFCD00011079
EINECS
232-237-2

Chemische Eigenschaften

Formel
LiClO4
Molmasse
106.40
Form
Lumps, Ampouled under argon
Schmelzpunkt
236°
Siedepunkt
400° dec.
Dichte
2.43
Storage & Sensitivity
Hygroscopic. Store under Argon. Ambient temperatures.
Löslichkeit
Partially soluble in water (30% at 25°, 72% at 100°). Soluble in alcohol, acetone, ether, ethyl acetate.

Anwendungen

Used as intermediates. An effective protein denaturant. It may be useful as a component in the development of biopolymers and biofilms. Acts as a catalyst in the solvent free thiolysis of epoxides. Used in various organic transformations.

Bemerkungen

Hygroscopic. Store under inert gas. Store away from incompatibles.

Literaturverweise

Mark A. Forman.; William P. Dailey. The lithium perchlorate-diethyl ether rate acceleration of the Diels-Alder reaction: Lewis acid catalysis by lithium ion.J. Am. Chem. Soc.1991,113(7), 2761-2762.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H272-H315-H319-H335

May intensify fire; oxidizer. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P221-P210v-P220-P305+P351+P338-P405-P501a

Take any precaution to avoid mixing with combustibles. Keep away from heat Keep/Store away from clothing/combustible materials. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Merck
14,5539
Gefahrenklasse
5.1
Verpackungsgruppe
II
Harmonized Tariff Code
2829.90
TSCA
Yes

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Chemikalien

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Metalle und Stoffe

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