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45525 Indium(III) fluoride, anhydrous, 99.95% (metals basis)

CAS-Nummer
7783-52-0
Synonyme

Stock No. Größe Preis ($) Menge Verfügbarkeit
45525-06 5g 77,40
45525-14 25g 350,00
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Indium(III) fluoride, anhydrous, 99.95% (metals basis)

MDL
MFCD00016149
EINECS
232-005-0

Chemische Eigenschaften

Formel
F3In
Molmasse
171.82
Form
Powder
Schmelzpunkt
ca 1170°
Siedepunkt
>1200°
Dichte
4.39
Storage & Sensitivity
Moisture Sensitive. Ambient temperatures.
Löslichkeit
Slightly soluble in water. Freely soluble in dilute acids.

Anwendungen

Indium(III) fluoride is used in the preparation of non-oxide glasses. It acts as a catalyst in the reaction of trimethylsilyl cyanide (TMSCN) to aldehydes to get cyanohydrins. It play a vital role as a catalyst in organic synthesis to prepare fluorine containing 2,4,5-trisubstituted imidazoles and polysubstituted pyrroles.

Bemerkungen

Moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents, acids, bases and metals.

Literaturverweise

Reddy, M. V.; Jeong, Y. T. Indium trifluoride: A highly efficient catalyst for the synthesis of fluorine-containing 2, 4, 5-trisubstituted imidazoles under solvent-free conditions. J. Fluorine Chem. 2012, 142, 45-51.

Suresh, R.; Muthusubramanian, S.; Nagaraj, M.; Manickam, G. Indium trichloride catalyzed regioselective synthesis of substituted pyrroles in water. Tetrahedron Lett. 2013, 54 (14), 1779-1784.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Merck
14,4959
Harmonized Tariff Code
2826.19
TSCA
Yes

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